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210056

Sigma-Aldrich

Potassium periodate

99.8%, ACS reagent

Sinonimo/i:

Periodic acid potassium salt, Potassium (meta)periodate

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100 G
107,00 €
500 G
376,00 €

About This Item

Formula condensata:
KIO4
Numero CAS:
Peso molecolare:
230.00
Numero CE:
Numero MDL:
Codice UNSPSC:
12352300
ID PubChem:
NACRES:
NA.21

107,00 €


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Grado

ACS reagent

Saggio

99.8%
99.8-100.3% (ACS specification)

Stato

powder

Impiego in reazioni chimiche

reagent type: oxidant

Impurezze

≤0.01% other halogens

pH

~5.1 (25 °C, 5 g/L)

Punto di fusione

582 °C (lit.)

Cationi in tracce

Mn: ≤1 ppm

Stringa SMILE

[K+].[O-]I(=O)(=O)=O

InChI

1S/HIO4.K/c2-1(3,4)5;/h(H,2,3,4,5);/q;+1/p-1
FJVZDOGVDJCCCR-UHFFFAOYSA-M

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Descrizione generale

Potassium periodate is widely used as an oxidizing agent.[1] It produces singlet oxygen (1O2) in alkaline medium via a non-photochemical pathway. This singlet oxygen can selectively oxidizes aqueous organic pollutants.[2]

Applicazioni

Potassium periodate may be employed as a chromogenic reagent for the sensitive estimation of phenothiazine drugs (either in pure form or in pharmaceutical formulations).[3] It may also be used in the following:
  • To compose silica-based slurries for polishing of ruthenium surface.[4]
  • To prepare slurry containing glycine for ruthenium and copper polishing.[5]
  • Spectrophotometric estimation of manganese in soil and fertilizer samples.4

Avvertenze

Danger

Indicazioni di pericolo

Classi di pericolo

Aquatic Acute 1 - Eye Dam. 1 - Ox. Sol. 1 - Skin Corr. 1C - STOT RE 1

Organi bersaglio

Thyroid

Codice della classe di stoccaggio

5.1A - Strongly oxidizing hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3


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I clienti hanno visto anche

Ruthenium polishing using potassium periodate as the oxidizer and silica abrasives.
Peethala BC and Babu SV.
Journal of the Electrochemical Society, 158(3), H271-H276 (2011)
Improved removal selectivity of ruthenium and copper by glycine in potassium periodate (KIO4)-based slurry.
Zeng X, et al.
Journal of the Electrochemical Society, 159(11), C525-C529 (2012)
Alok D Bokare et al.
Environmental science & technology, 49(24), 14392-14400 (2015-11-26)
A nonphotochemical generation of singlet oxygen ((1)O2) using potassium periodate (KIO4) in alkaline condition (pH > 8) was investigated for selective oxidation of aqueous organic pollutants. The generation of (1)O2 was initiated by the spontaneous reaction between IO4(-) and hydroxyl
Milne GWA.
Gardner's Commercially Important Chemicals: Synonyms, Trade Names, and Properties, 513-513 (2005)
Determination of some phenothiazine drugs based on colour reaction with potassium periodate.
Basavaiah K, et al.
Analytical Letters, 33(1), 43-51 (2000)

Domande

1–2 di 2 domande  
  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta
    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta
    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

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