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M188

Sigma-Aldrich

Maleic anhydride

99%

Sinonimo/i:

2,5-Furandione

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25 G
54,50 €
1 KG
78,60 €
5 KG
105,00 €
25 KG
642,00 €

54,50 €

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Cambia visualizzazione
25 G
54,50 €
1 KG
78,60 €
5 KG
105,00 €
25 KG
642,00 €

About This Item

Formula empirica (notazione di Hill):
C4H2O3
Numero CAS:
108-31-6
Peso molecolare:
98.06
Beilstein:
106909
Numero CE:
203-571-6
Numero MDL:
MFCD00005518
Codice UNSPSC:
12162002
ID PubChem:
24896701
NACRES:
NA.23

54,50 €

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Densità del vapore

3.4 (vs air)

Tensione di vapore

0.16 mmHg ( 20 °C)

Saggio

99%

Temp. autoaccensione

870 °F

Limite di esplosione

7.1 %

P. ebollizione

200 °C (lit.)

Punto di fusione

51-56 °C (lit.)

Stringa SMILE

O=C1OC(=O)C=C1

InChI

1S/C4H2O3/c5-3-1-2-4(6)7-3/h1-2H
FPYJFEHAWHCUMM-UHFFFAOYSA-N

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Categorie correlate

Descrizione generale

Maleic anhydride (MA) belongs to the class of monomers known as cyclic dicarboxylic anhydrides. It is commonly used in polymerization reactions to produce various types of polymers such as poly(maleic anhydride) (PMA), maleic anhydride-based resins, and maleic anhydride-butadiene copolymers (MABS), etc. These MA-based polymers find applications in various fields including, polymer blends and coatings, epoxy resins, semiconductor devices, secondary batteries, lithium-ion batteries, resin films, glass fiber, coatings, packaging, water treatment, and drug delivery systems. Additionally, MA can be grafted onto other polymers, to enhance their performance and compatibility with other materials. Grafted polymers find applications in the automotive, packaging, and construction industries. Maleic anhydride is also used as an electron-acceptor monomer in the development of various antimicrobial polymers due to their reactive double bonds and reactive anhydride groups.[1][2][3][4][5]

The structure of maleic acid consists of four carbon molecules along with carboxylate groups on either ends, with a double bond between the central carbon atoms. The anhydride of maleic acid has five atoms in its cyclic molecule, the unsaturated bond undergoes free radical polymerization in the presence of an initiator.

Applicazioni

Maleic anhydride can be used as a monomer:
  • In the grafting process of high-density polyethylene (HDPE) by the monomer microencapsulation technique, which enables the introduction of enhanced functionality and improved properties to the polymer for functional coatings, membranes, or surface treatments, adhesives, and coatings.
  • In the functionalization of polylactic acid (PLA) and acts as a coupling agent in natural fiber biocomposites. The functionalization improves the compatibility and interfacial adhesion between PLA and natural fibers, leading to enhanced mechanical properties and expanded applications of the resulting biocomposite materials.
  • Maleic anhydride may be used in the synthesis of unsaturated polyester resins and as a reactant in synthesizing important products such as agricultural chemicals, lubricant additives, and food acidulatents.

Stato fisico

briquettes

Avvertenze

Danger

Indicazioni di pericolo

H302,H314,H317,H334,H372

Classi di pericolo

Acute Tox. 4 Oral - Eye Dam. 1 - Resp. Sens. 1 - Skin Corr. 1B - Skin Sens. 1A - STOT RE 1 Inhalation

Organi bersaglio

Respiratory system

Rischi supp

EUH071

Codice della classe di stoccaggio

6.1C - Combustible acute toxic Cat.3 / toxic compounds or compounds which causing chronic effects

Classe di pericolosità dell'acqua (WGK)

WGK 1

Punto d’infiammabilità (°F)

217.4 °F - closed cup

Punto d’infiammabilità (°C)

103 °C - closed cup

Dispositivi di protezione individuale

Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges

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Certificati d'analisi (COA)

Lot/Batch Number
MKCX5330
SDBB3002
MKCV5024
STBL3785
STBL4342

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Veronika Bátori et al.
Polymers, 11(3) (2019-04-10)
This study was conducted to improve the properties of thin films prepared from orange waste by the solution casting method. The main focus was the elimination of holes in the film structure by establishing better cohesion between the major cellulosic
João F A Silva et al.
Polymers, 12(6) (2020-06-18)
Titanium dioxide is considered the most efficient white pigment for opacification of thermoplastics. However, its high cost, combined with strong price oscillations due to production bottlenecks, has been driving the industry towards alternatives that might allow reducing the titanium dioxide
Sylwia Członka et al.
Materials (Basel, Switzerland), 13(7) (2020-04-16)
In this work, rigid polyurethane (PUR) foams were prepared by incorporating 2 wt% of eucalyptus fibers. The eucalyptus fibers were surface-modified by maleic anhydride, alkali, and silane (triphenylsilanol) treatment. The impact of the modified eucalyptus fibers on the mechanical, thermal
Eunice Cunha et al.
Nanomaterials (Basel, Switzerland), 8(9) (2018-09-12)
The search for graphene or few-layer graphene production methods that are simple, allow mass production, and yield good quality material continues to provoke intense investigation. The present work contributes to this investigation through the study of the aqueous exfoliation of
Frita Yuliati et al.
Polymers, 12(8) (2020-08-06)
Low cross-link density thermally reversible networks were successfully synthesized from jatropha and sunflower oils. The oils were epoxidized and subsequently reacted with furfurylamine to attach furan groups onto the triglycerides, preferably at the epoxide sites rather than at the ester
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Domande

1–4 di 4 domande  

  1. How can I determine the shelf life / expiration / retest date of this product?

    1 risposta

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

      Utile?

  2. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 risposta

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

      Utile?

  3. Could you please provide the approx. particle size of the briquets?

    1 risposta

    1. These briquettes are shaped like a 'Charcoal' briquette with approximate dimensions of 32mm x 28mm x 12 mm.

      Utile?

  4. What use in ABS and PC

    1 risposta

    1. Please see the amended response. It is advised that applications for Product M188 be searched via literature search. The cited articles may assist in your literature search for Maleic anhydride uses with polycarbonate and acrylonitrile butadiene styrene.

      https://doi.org/10.1007/s10965-021-02632-9)
      https://doi.org/10.1016/j.matpr.2021.01.531
      https://doi.org/10.1016/j.polymer.2004.07.022

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