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Sigma-Aldrich

Cobalt(II) nitrate hexahydrate

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≥99.9% trace metals basis

Sinonimo/i:

Cobalt Nitrate Hexahydrate, Cobalt dinitrate hexahydrate, Cobaltous nitrate, Cobaltous nitrate hexahydrate, Nitric acid, cobalt(II) salt

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25 G
103,00 €
250 G
216,00 €

About This Item

Formula condensata:
Co(NO3)2 · 6H2O
Numero CAS:
Peso molecolare:
291.03
Numero MDL:
Codice UNSPSC:
12352302
NACRES:
NA.21

103,00 €


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Grado

for analytical purposes

Livello qualitativo

Saggio

≥99.9% trace metals basis

Stato

powder, crystals or granules (Chunks)

Caratteristiche più verdi

Design for Energy Efficiency
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Colore

faint red to very dark red

Punto di fusione

55 °C (lit.)

Solubilità

soluble, clear to slightly hazy

Categoria alternativa più verde

Stringa SMILE

O.O.O.O.O.O.[Co++].[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Co.2NO3.6H2O/c;2*2-1(3)4;;;;;;/h;;;6*1H2/q+2;2*-1;;;;;;
QGUAJWGNOXCYJF-UHFFFAOYSA-N

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Descrizione generale

Cobalt(II)nitrate hexahydrate is red solid which is soluble in water and polar solvents. It is also known as hexaaquacobalt(II) nitrate consists of [Co(OH2)6]2+ and [NO3]ions.
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Applicazioni

Cobalt(II) nitrate hexahydrate, has been widely used for the synthesis of Cobalt oxide nanoparticles and cobalt containing compounds. For Example:Cobalt(II) nitrate hexahydrate is used to synthesize cobalt-cobalt oxide/N-doped carbon hybrids, which are then used as hydrogen evolution reaction (HER) or superior oxygen evolution reaction (OER) catalysts in water splitting.[1]

It has also been used as a primary precursor material in the synthesis of Co3O4 nanocrystals in various shapes such as nanosheets, nanocubes, and nanobelts as a catalyst for methane combustion.[2]

Furthermore, the reaction of Cobalt(II) nitrate hexahydrate with Nickel(II) nitrate hexahydrate produces Nickel-cobalt layered double hydroxide nanosheets in presence of methanol and CTAB, which is used as a high-performance electrocatalyst for oxygen evolution.[3]

In addition, Cobalt(II) nitrate hexahydrate precursor powder is calcined to produce Co3O4 nanotubes using the template synthesis method. The Co3O4 nano-tubes, nanorods, and nanoparticles that have been created are used in gas sensing systems and as anode materials for Li-ion batteries[4]

Cobalt hydroxide and layered double hydroxides (CH@LDH) have been synthesized using Cobalt(II)nitrate hexahydrate as a sulfur host for lithium–sulfur batteries.[5]

It is well studied that, Cobalt(II) nitrate hexahydrate is used as a heterogeneous catalyst Co/SiO2 with Silica support, for Fischer−Tropsch Synthesis.[6]

Cobalt(II) Nitrate Hexahydrate is also used as a catalyst for the synthesis of 5-Carboxanilide-dihydropyrimidinone derivatives by the condensation reaction of acetoacetanilide, aldehyde and urea/thiourea.[7]

Avvertenze

Danger

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1B Inhalation - Eye Dam. 1 - Muta. 2 - Ox. Sol. 2 - Repr. 1B - Resp. Sens. 1 - Skin Sens. 1 - STOT RE 2 Inhalation

Organi bersaglio

Lungs

Codice della classe di stoccaggio

5.1B - Oxidizing hazardous materials

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Elenchi normativi

Forniamo informazioni su eventuali restrizioni prevalentemente per i prodotti chimici. Per altre tipologie di prodotto siamo in grado di fornire soltanto informazioni limitate. Nessuna segnalazione significa che nessuno dei componenti è citato in un elenco. È dovere dell’utilizzatore assicurarsi che il prodotto venga impiegato in maniera sicura e a norme di legge.

EU REACH SVHC Candidate List

CAS No.

EU REACH Annex XVII (Restriction List)

CAS No.

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Nickel?cobalt layered double hydroxide nanosheets as high-performance electrocatalyst for oxygen evolution reaction
Jiang J, et al.
Journal of Power Sources, 278, 445-451 (2015)
Fundamentals of melt infiltration for the preparation of supported metal catalysts. The case of Co/SiO2 for Fischer-Tropsch synthesis
Eggenhuisen T M, et al.
Journal of the American Chemical Society, 132, 18318-18325 (2010)
Co3O4 Nanomaterials in Lithium-Ion Batteries and Gas Sensors
Li W Y, et al.
Advanced Functional Materials , 15, 851-857 (2005)
In situ cobalt-cobalt oxide/N-doped carbon hybrids as superior bifunctional electrocatalysts for hydrogen and oxygen evolution
Jin H, et al.
Journal of the American Chemical Society, 137, 2688-2694 (2015)
Double-Shelled Nanocages with Cobalt Hydroxide Inner Shell and Layered Double Hydroxides Outer Shell as High-Efficiency Polysulfide Mediator for Lithium-Sulfur Batteries
Zhang J, et al.
Angewandte Chemie (International ed. in English), 55, 3982-3986 (2016)

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