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Key Documents

704091

Sigma-Aldrich

Tributyltin hydride solution

1 M in cyclohexane

Sinonimo/i:

Tributylstannane, Tributylstannyl hydride

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About This Item

Formula empirica (notazione di Hill):
C12H28Sn
Numero CAS:
Peso molecolare:
291.06
Numero MDL:
Codice UNSPSC:
12352103
ID PubChem:
NACRES:
NA.22

Forma fisica

liquid

Impiego in reazioni chimiche

reagent type: reductant

Concentrazione

1 M in cyclohexane

Indice di rifrazione

n20/D 1.438

Densità

0.895 g/mL at 25 °C

Stringa SMILE

CCCC[SnH](CCCC)CCCC

InChI

1S/3C4H9.Sn.H/c3*1-3-4-2;;/h3*1,3-4H2,2H3;;
DBGVGMSCBYYSLD-UHFFFAOYSA-N

Applicazioni

Reactant or reagent for:
  • Alkyne hydrostannations
  • Intramolcular cyclization for the synthesis of zoanthamine alkaloids
  • Stereoselective C-glycosylation of pyranosides using Heck allylation
  • Synthesis of phenylbutenoid dimers for use in treating diseases
  • Preparation of N-acyl derivatives of ecteinascidin 770
  • Syntehsis of cyclonucleosides using black light induced radical cyclization

Avvertenze

Danger

Classi di pericolo

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Eye Irrit. 2 - Flam. Liq. 2 - Repr. 1B - Skin Irrit. 2 - STOT RE 1 - STOT SE 3

Organi bersaglio

Respiratory system

Codice della classe di stoccaggio

3 - Flammable liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

5.0 °F

Punto d’infiammabilità (°C)

-15 °C


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Cassander P Titley-O'Neal et al.
The Science of the total environment, 449, 52-62 (2013-02-16)
Queen conch (Strombus gigas) are listed in CITES Appendix II. Populations may be declining due to anthropogenic inputs that include pollutants from boating activity. In the British Virgin Islands (BVI), some conch exhibit imposex, a condition in which male external
Shanshan Zhu et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 921-922, 21-26 (2013-02-19)
Analysis of tributyltin chloride (TBT) in environmental samples, such as seawater, is important in order to evaluate the TBT contamination and accumulation in the trophic chain. The environmental impact of organotin compounds has been a particular focus of analytical studies.
Detection, monitoring, and control of tributyltin--an almost complete success story.
Peter Matthiessen
Environmental toxicology and chemistry, 32(3), 487-489 (2013-02-19)
Robert W Chapman et al.
Molecular ecology, 22(6), 1485-1487 (2013-04-20)
Reproduction is the goal of living organisms, and environmental conditions that influence sexual development are therefore critical to understanding adaptation in natural populations. It is not surprising that so much attention has been devoted to the impacts of the physical
Ang Yu et al.
Aquatic toxicology (Amsterdam, Netherlands), 128-129, 158-162 (2013-01-15)
Tributyltin (TBT) is a ubiquitous marine contaminant due to its extensive use as a biocide, fungicide and antifouling agent. However, the neurotoxic effect of TBT has not been extensively studied, especially in marine fish. This study was conducted to investigate

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