692336

RUCL₂[(R)(DM−SEGPHOS)][(R,(R))(DPEN)]

• Sinonimo/i: Dichloro[(R)−5,5′−bis[di(3,5−xylyl)phosphino]−4,4′−bi−1,3−benzodioxole][1R,2R−1,2−diphenylethylenediamine]ruthenium(ΙΙ)
• Formula empirica (notazione di Hill): C₆₀H₆₀Cl₂N₂O₄P₂Ru
• Numero CAS: 944450-45-7
• Peso molecolare: 1107.05
• Numero MDL: MFCD09753031
• Codice UNSPSC: 12352005
• ID PubChem: 329761484
• NACRES: NA.22

Proprietà

• Forma fisica: powder
• Temperatura di conservazione: 2-8°C
• Stringa SMILE: Cl[Ru]Cl.N[C@@H]([C@H](N)c1ccccc1)c2ccccc2.Cc3cc(C)cc(c3)P(c4cc(C)cc(C)c4)c5ccc6OCOc6c5-c7c8OCOc8ccc7P(c9cc(C)cc(C)c9)c%10cc(C)cc(C)c%10
• InChI: 1S/C46H44O4P2.C14H16N2.2ClH.Ru/c1-27-13-28(2)18-35(17-27)51(36-19-29(3)14-30(4)20-36)41-11-9-39-45(49-25-47-39)43(41)44-42(12-10-40-46(44)50-26-48-40)52(37-21-31(5)15-32(6)22-37)38-23-33(7)16-34(8)24-38;15-13(11-7-3-1-4-8-11)14(16)12-9-5-2-6-10-12;;;/h9-24H,25-26H2,1-8H3;1-10,13-14H,15-16H2;2*1H;/q;;;;+2/p-2/t;13-,14-;;;/m.1.../s1; FOEKPXQPRAIJRW-ODQAEMFESA-L

Descrizione

Applicazioni

Takasago Ligands and Complexes for Asymmetric Reactions

RuCl₂[(R)-(DM-SEGPHOS^®)][(R,(R))-(DPEN)] can be used as a catalyst in the enantioselective preparation of chiral amino alcohols and their derivatives by asymmetric hydrogenation of various amino ketones using mild hydrogen pressure.

Note legali

Sold in collaboration with Takasago for research purposes only. JP Registration No. 3148136 JP Application No. 19970359654

SEGPHOS is a registered trademark of Takasago Intl. Corp.

Informazioni sulla sicurezza

• Codice della classe di stoccaggio: 13 - Non Combustible Solids
• Classe di pericolosità dell'acqua (WGK): WGK 3
• Punto d’infiammabilità (°F): Not applicable
• Punto d’infiammabilità (°C): Not applicable