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633216

Sigma-Aldrich

5,5′′′′′-Dihexyl-2,2′:5′,2′′:5′′,2′′′:5′′′,2′′′′:5′′′′,2′′′′′-sexithiophene

electron donor for OPV devices

Sinonimo/i:

α,ω-Dihexylsexithiophene, DH-6T

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About This Item

Formula empirica (notazione di Hill):
C36H38S6
Numero CAS:
151271-43-1
Peso molecolare:
663.08
Numero MDL:
MFCD06411295
Codice UNSPSC:
12352103
ID PubChem:
24882543
NACRES:
NA.23

Forma fisica

solid

Punto di fusione

280 °C (dec.) (lit.)

Solubilità

chlorobenzene: soluble (soluble)
chloroform: slightly soluble
methylene chloride: slightly soluble

Energia dell’orbitale

HOMO 5.2 eV 
LUMO 2.9 eV 

Prestazioni di un dispositivo OPV

ITO/DH6T/PC61BM/Al

  • Short-circuit current density (Jsc): 0.027 mA/cm2
  • Open-circuit voltage (Voc): 0.18 V
  • Fill Factor (FF): 0.33
  • Power Conversion Efficiency (PCE): 0.002 %

ITO/PEDOT:PSS/DH6T/PC61BM/Al
  • Short-circuit current density (Jsc): 0.04 mA/cm2
  • Open-circuit voltage (Voc): 0.24 V
  • Fill Factor (FF): 0.36
  • Power Conversion Efficiency (PCE): 0.004 %

ITO/PEDOT:PSS/DH6T:PC61BM (1:1)/Al
  • Short-circuit current density (Jsc): 0.097 mA/cm2
  • Open-circuit voltage (Voc): 0.36 V
  • Fill Factor (FF): 0.24
  • Power Conversion Efficiency (PCE): 0.01 %

Caratteristiche del semiconduttore

P-type (mobility=0.13 cm2/V·s)

Stringa SMILE

CCCCCCc1ccc(s1)-c2ccc(s2)-c3ccc(s3)-c4ccc(s4)-c5ccc(s5)-c6ccc(CCCCCC)s6

InChI

1S/C36H38S6/c1-3-5-7-9-11-25-13-15-27(37-25)29-17-19-31(39-29)33-21-23-35(41-33)36-24-22-34(42-36)32-20-18-30(40-32)28-16-14-26(38-28)12-10-8-6-4-2/h13-24H,3-12H2,1-2H3
QCMASTUHHXPVGT-UHFFFAOYSA-N

Descrizione generale

5,5′′′′′-Dihexyl-2,2′:5′,2′′:5′′,2′′′:5′′′,2′′′′:5′′′′,2′′′′′-sexithiophene (DH6T) is an alkyl substituted oligothiophene that can be used as an organic semiconductor. It has a field mobility of 1 cm2/Vs that makes it a suitable active layered material in electronic and optoelectronic applications.

Applicazioni

DH6T can be used as a p-type donor molecule for the fabrication of organic electronic devices such as organic field effect transistors (OFETs), thin film transistors (TFTs) and organic solar cells (OSCs).

Codice della classe di stoccaggio

11 - Combustible Solids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable

Dispositivi di protezione individuale

Eyeshields, Gloves, type N95 (US)

Certificati d'analisi (COA)

Cerca il Certificati d'analisi (COA) digitando il numero di lotto/batch corrispondente. I numeri di lotto o di batch sono stampati sull'etichetta dei prodotti dopo la parola ‘Lotto’ o ‘Batch’.

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Photovoltaic performance of organic solar cells based on DH6T/PCBM thin film active layers
Muhammad FF and Sulaiman K
Thin Solid Films, 519(15), 5230-5233 (2011)
Relationship between molecular structure and electrical performance of oligothiophene organic thin film transistors
Halik M, et al.
Advanced Materials, 15(11), 917-922 (2003)
High Hole Mobility and Thickness-Dependent Crystal Structure in alpha, omega-Dihexylsexithiophene Single-Monolayer Field-Effect Transistors
Mannebach EM, et al.
Advances in Functional Materials, 23(5), 554-564 (2013)
All organic near ultraviolet photodetectors based on bulk hetero-junction of P3HT and DH6T
Shalu C, et al.
Semiconductor Science and Technology, 33(9), 095021-095021 (2018)
Photovoltaic performance of organic solar cells based on DH6T/PCBM thin film active layers
Muhammad, F. F.; et al.
Thin Solid Films, 519, 5230-5233 (2011)
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