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Sigma-Aldrich

Octafluoro-1,4-diiodobutane

98%

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About This Item

Formula condensata:
I(CF2)4I
Numero CAS:
Peso molecolare:
453.84
Numero CE:
Numero MDL:
Codice UNSPSC:
12352100
ID PubChem:
NACRES:
NA.22

Saggio

98%

Indice di rifrazione

n20/D 1.429 (lit.)

P. eboll.

150 °C (lit.)

Punto di fusione

−9 °C (lit.)

Densità

2.474 g/mL at 25 °C (lit.)

Stringa SMILE

FC(F)(I)C(F)(F)C(F)(F)C(F)(F)I

InChI

1S/C4F8I2/c5-1(6,3(9,10)13)2(7,8)4(11,12)14
JILAKKYYZPDQBE-UHFFFAOYSA-N

Descrizione generale

Octafluoro-1,4-diiodobutane (ofib, C4F8I2) is also referred to as 1,1,2,2,3,3,4,4-octafluoro-1,4-diiodobutane. It acts as a halogen bond donor compound and its cocrystallization with methyldiphenylphosphine oxide (mdppo) has been investigated. In combination with a calixcrown compound ofib forms a ′binary host′ system, which is employed for the isolation of cesium iodide from aqueous to fluorous phase.

Applicazioni

Octafluoro-1,4-diiodobutane may be used as a guest molecule to prepare a chiral bidentate inclusion complex with pyridyl moieties of a pyridoallenoacetylenic host. It may be employed in the synthesis of three-component supramolecular complexes.

Codice della classe di stoccaggio

10 - Combustible liquids

Classe di pericolosità dell'acqua (WGK)

WGK 3

Punto d’infiammabilità (°F)

Not applicable

Punto d’infiammabilità (°C)

Not applicable


Certificati d'analisi (COA)

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Switching between halogen-and hydrogen-bonding in stoichiometric variations of a cocrystal of a phosphine oxide.
Oh SY, et al.
CrystEngComm, 14(19), 6110-6114 (2012)
Metric engineering of supramolecular Borromean rings.
Liantonio R, et al.
Chemical Communications (Cambridge, England), 17, 1819-1821 (2006)
Dipyridinocalixcrown/diiodoperfluorocarbon binary host systems for CsI: structural studies and fluorous phase extraction of caesium.
Gattuso G, et al.
Tetrahedron, 63(23), 4951-4958 (2007)
Silvia Castro-Fernández et al.
Organic letters, 16(4), 1136-1139 (2014-02-12)
A chiral bidentate inclusion complex has been formed by halogen-bond interaction between the pyridyl moieties of a pyridoallenoacetylenic host and octafluorodiiodobutane. X-ray crystallography showed that the guest adopts a chiral conformation inside the molecular channels formed by stacking of the
Chang Wang et al.
Environmental health perspectives, 120(1), 119-125 (2011-10-13)
Polyfluorinated iodine alkanes (PFIs) are important intermediates in the synthesis of organic fluoride products. Recently, PFIs have been detected in fluoropolymers as residual raw materials, as well as in the ambient environment. High production volumes and potential environmental releases of

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