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25102

Sigma-Aldrich

9-(Chloromethyl)anthracene

BioReagent, suitable for fluorescence, ≥97.0% (AT)

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About This Item

Empirical Formula (Hill Notation):
C15H11Cl
CAS Number:
24463-19-2
Molecular Weight:
226.70
Beilstein:
1873394
EC Number:
246-274-7
MDL number:
MFCD00001263
UNSPSC Code:
12352200
PubChem Substance ID:
329752775

product line

BioReagent

Assay

≥97.0% (AT)

mp

138-140 °C (lit.)

fluorescence

λex 356 nm; λem 412 nm (after derivatisation with sodium acetate)

suitability

suitable for fluorescence

SMILES string

ClCc1c2ccccc2cc3ccccc13

InChI

1S/C15H11Cl/c16-10-15-13-7-3-1-5-11(13)9-12-6-2-4-8-14(12)15/h1-9H,10H2

InChI key

PCVRSXXPGXRVEZ-UHFFFAOYSA-N

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Analysis Note

In addition to the emission maximum at 412 nm, there are lower maxima at 434, 395 and 459 nm.

Other Notes

Blocking group reagent for carboxylic acids, phenols, thiophenols and mercaptans[1]; Derivatizing agent for carboxylic acids giving esters with enhanced UV and fluorescence detection in HPLC[2]

Pictograms

Exclamation mark
GHS07

Signal Word

Warning

Hazard Statements

H315,H319,H335

Hazard Classifications

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

Target Organs

Respiratory system

Storage Class Code

8A - Combustible corrosive hazardous materials

WGK

WGK 3

Flash Point(F)

Not applicable

Flash Point(C)

Not applicable

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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W.D. Korte
Journal of Chromatography A, 243, 153-153 (1982)
Zhenming Xie et al.
Journal of chromatography. B, Analytical technologies in the biomedical and life sciences, 857(1), 53-58 (2007-08-21)
A rapid and sensitive RP-HPLC method with fluorescence detection has been developed for the quantitative analysis of trace amounts of monofluoroacetate (MFA) in biological samples as serum, food and meat. 9-Chloromethylanthracene (9-CMA) is used as the fluorescence labeling reagent. Samples
J F Lawrence et al.
Journal of chromatography. A, 721(2), 359-364 (1996-01-19)
The reagent 9-chloromethylanthracene was evaluated for derivatization of the diarrhetic shellfish poisons, okadaic acid and dinophysistoxin-1 (DTX-1), to form fluorescent products separable by liquid chromatography. The toxins were reacted with the reagent in acetonitrile in the presence of tetramethylammonium hydroxide
Zhenming Xie et al.
Journal of chromatographic science, 50(6), 464-468 (2012-04-14)
A simple and sensitive high-performance liquid chromatography (HPLC) method is proposed for the analysis of some carboxylic acids in food samples and the environment. The use of 9-chloromethyl anthracene as a fluorescence-labeling reagent has been investigated. The derivatization reagent reacts
Ying Zhang et al.
Colloids and surfaces. B, Biointerfaces, 44(2-3), 104-109 (2005-07-26)
Polymeric micelles based on amphiphilic diblock copolymers methoxy poly(ethylene glycol)-polylactide with various hydrophobic lengths were designed as carriers of poorly water-soluble anticancer drug methotrexate (MTX). Relationship between physicochemical characteristics of micelles and release behavior was explored. The critical micelle concentration
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