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F1506

Sigma-Aldrich

9-Fluorenone

98%

Synonym(s):

9H-Fluorene-9-one, Fluoren-9-one (8CI)

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HUF 9,580.00
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HUF 28,000.00
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HUF 47,300.00

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5 G
HUF 9,580.00
100 G
HUF 28,000.00
500 G
HUF 47,300.00

About This Item

Empirical Formula (Hill Notation):
C13H8O
CAS Number:
486-25-9
Molecular Weight:
180.20
Beilstein:
1636531
EC Number:
207-630-7
MDL number:
MFCD00001141
UNSPSC Code:
12352100
PubChem Substance ID:
24894771
NACRES:
NA.22
Assay:
98%

HUF 9,580.00

Please contact Customer Service for Availability
Request a Bulk Order

Quality Level

200

Assay

98%

bp

342 °C (lit.)

mp

80-83 °C (lit.)

SMILES string

O=C1c2ccccc2-c3ccccc13

InChI

1S/C13H8O/c14-13-11-7-3-1-5-9(11)10-6-2-4-8-12(10)13/h1-8H

InChI key

YLQWCDOCJODRMT-UHFFFAOYSA-N

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Application

9-Fluorenone has been extensively used as a precursor to synthesize a variety of organic electronic materials.[1][2][3] Some of the general examples are:
  • Synthesis of host for the blue and green phosphorescent organic light emitting diodes (PHOLEDs).[1][2][4]
  • Synthesis of fluorene-based molecular motors.[5]
  • Synthesis of open-shell Chichibabin′s hydrocarbons as potential organic spintronic materials.[3]
  • It also acts as a sensitizer in the formation of picene via photosensitization of 1,2-di(1-naphthyl)ethane.[6]

Pictograms

Exclamation markEnvironment
GHS07,GHS09

Signal Word

Warning

Hazard Statements

H319,H411

Hazard Classifications

Aquatic Chronic 2 - Eye Irrit. 2

Storage Class Code

11 - Combustible Solids

WGK

WGK 3

Flash Point(F)

325.4 °F

Flash Point(C)

163 °C

Personal Protective Equipment

dust mask type N95 (US), Eyeshields, Gloves

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Certificates of Analysis (COA)

Lot/Batch Number
SDBB0511
STBK8593
STBK2859
STBJ8951
STBJ1746

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Stable Tetrabenzo-Chichibabin?s hydrocarbons: tunable ground state and unusual transition between their closed-shell and open-shell resonance forms.
Zeng Z, et al.
Journal of the American Chemical Society, 134(35), 14513-14525 (2012)
Facile synthesis of picene from 1, 2-di (1-naphthyl) ethane by 9-fluorenone-sensitized photolysis.
Okamoto H, et al.
Organic Letters, 13(10), 2758-2761 (2011)
Yufang Liu et al.
Journal of computational chemistry, 30(16), 2723-2727 (2009-04-29)
The geometric structures and infrared (IR) spectra in the electronically excited state of a novel doubly hydrogen-bonded complex formed by fluorenone and alcohols, which has been observed by IR spectra in experimental study, are investigated by the time-dependent density functional
Novel carbazole/fluorene hybrids: Host materials for blue phosphorescent OLEDs.
Shih P I, et al.
Organic Letters, 8(13), 2799-2802 (2006)
Dustin Pagoria et al.
Biomaterials, 26(19), 4091-4099 (2005-01-25)
Recent evidence suggests that following visible-light (VL) irradiation, CQ and the CQ-related photosensitizers benzil (BZ), benzophenone (BP), and 9-fluorenone (9-F) generate initiating radicals that may indiscriminately react with molecular oxygen forming reactive oxygen species (ROS). The purpose of this investigation
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  1. How is shipping temperature determined? And how is it related to the product storage temperature?

    1 answer

    1. Products may be shipped at a different temperature than the recommended long-term storage temperature. If the product quality is sensitive to short-term exposure to conditions other than the recommended long-term storage, it will be shipped on wet or dry-ice. If the product quality is NOT affected by short-term exposure to conditions other than the recommended long-term storage, it will be shipped at ambient temperature. As shipping routes are configured for minimum transit times, shipping at ambient temperature helps control shipping costs for our customers. For more information, please refer to the Storage and Transport Conditions document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/316/622/storage-transport-conditions-mk.pdf

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  2. How can I determine the shelf life / expiration / retest date of this product?

    1 answer

    1. If this product has an expiration or retest date, it will be shown on the Certificate of Analysis (COA, CofA). If there is no retest or expiration date listed on the product's COA, we do not have suitable stability data to determine a shelf life. For these products, the only date on the COA will be the release date; a retest, expiration, or use-by-date will not be displayed.
      For all products, we recommend handling per defined conditions as printed in our product literature and website product descriptions. We recommend that products should be routinely inspected by customers to ensure they perform as expected.
      For products without retest or expiration dates, our standard warranty of 1 year from the date of shipment is applicable.
      For more information, please refer to the Product Dating Information document: https://www.sigmaaldrich.com/deepweb/assets/sigmaaldrich/marketing/global/documents/449/386/product-dating-information-mk.pdf

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