905119
all-cis-Hexafluorocylclohexane
Sinónimos:
all-cis-1,2,3,4,5,6-Hexafluorocyclohexane
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About This Item
Fórmula empírica (notación de Hill):
C6H6F6
Número de CAS:
Peso molecular:
192.10
UNSPSC Code:
12352101
NACRES:
NA.22
Productos recomendados
form
solid
mp
289-290 °C
functional group
fluoro
storage temp.
2-8°C
Categorías relacionadas
Application
The incorporation of fluorine in agrochemical and pharmaceutical compounds is of high interest due to the ability to fine-tune the polarity, pKA-value, conformation and metabolic stability. Derived from a cis-selective hydrogenation developed by Glorius and co-workers, this fluorinated compound displays a diverse utility as a building block for chemical synthesis. All-cis-multifluorinated cyclohexanes are of great interest in material chemistry. All-cis-1,2,3,4,5,6-hexafluorocyclohexane, which has been referred to as “Janus-headed” molecule, is one of the most polar compounds known. Liquid crystalline materials are known applications for all-cis-multifluorinated cyclohexanes.
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Storage Class
11 - Combustible Solids
wgk_germany
WGK 3
flash_point_f
Not applicable
flash_point_c
Not applicable
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Neil S Keddie et al.
Nature chemistry, 7(6), 483-488 (2015-05-21)
The highest-energy stereoisomer of 1,2,3,4,5,6-hexafluorocyclohexane, in which all of the fluorines are 'up', is prepared in a 12-step protocol. The molecule adopts a classic chair conformation with alternate C-F bonds aligned triaxially, clustering three highly electronegative fluorine atoms in close
Mario P Wiesenfeldt et al.
Science (New York, N.Y.), 357(6354), 908-912 (2017-08-12)
All-cis-multifluorinated cycloalkanes exhibit intriguing electronic properties. In particular, they display extremely high dipole moments perpendicular to the aliphatic ring, making them highly desired motifs in material science. Very few such motifs have been prepared, as their syntheses require multistep sequences
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