90383

Chlorotriethylsilane

for GC derivatization, LiChropur^™, ≥97.0% (GC)

• Sinónimos: TESCl, Triethylchlorosilane
• Fórmula lineal: (C₂H₅)₃SiCl
• Número de CAS: 994-30-9
• Peso molecular: 150.72
• Beilstein/REAXYS Number: 1732860
• EC Number: 213-615-6
• MDL number: MFCD00000507
• UNSPSC Code: 12000000
• PubChem Substance ID: 329769905
• NACRES: NA.22

Propiedades

• grade: for GC derivatization
• Quality Level: 100
• assay: ≥97.0% (GC)
• form: liquid
• quality: LiChropur^™
• reaction suitability: reagent type: derivatization reagent; reaction type: Silylations
• technique(s): gas chromatography (GC): suitable
• refractive index: n20/D 1.43 (lit.)
• bp: 142-144 °C (lit.)
• density: 0.898 g/mL at 25 °C (lit.)
• SMILES string: CC[Si](Cl)(CC)CC
• InChI: 1S/C6H15ClSi/c1-4-8(7,5-2)6-3/h4-6H2,1-3H3
• InChI key: DCFKHNIGBAHNSS-UHFFFAOYSA-N

Descripción

General description

Chlorotriethylsilane may be used as a silylating reagent for the preparation of trisilyl ethers from alcohols in the presence of a base such as imidazole, pyridine or 4-(dimethylamino)pyridine. It is found to be more reactive when used with pyridine as a solvent.

Application

Chlorotriethylsilane may be used as a derivatizing reagent for the determination of fluoride, in toothpaste samples using headspace solid-phase microextraction and gas chromatography–flame ionization detection.

Other Notes

Los agentes sililantes presentan algunas ventajas sobre los trimetilsilil para aplicaciones de síntesis y analíticas

Legal Information

LiChropur is a trademark of Merck KGaA, Darmstadt, Germany

Información de seguridad

• pictograms: GHS02,GHS05,GHS06
• signalword: Danger
• hcodes: H226 - H301 - H314
• pcodes: P210 - P280 - P301 + P310 + P330 - P303 + P361 + P353 - P305 + P351 + P338 + P310
• Hazard Classifications: Acute Tox. 3 Oral - Eye Dam. 1 - Flam. Liq. 3 - Skin Corr. 1A
• supp_hazards: EUH014 - EUH071
• Storage Class: 3 - Flammable liquids
• wgk_germany: WGK 1
• flash_point_f: 86.0 °F
• flash_point_c: 30 °C
• ppe: Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter