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375187

Sigma-Aldrich

Trimethyltin chloride solution

1.0 M in hexanes

Sinónimos:

Chlorotrimethylstannane, Chlorotrimethyltin, Trimethylchlorostannane, Trimethylchlorotin, Trimethylstannyl chloride, Trimethyltin chloride

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About This Item

Fórmula lineal:
(CH3)3SnCl
Número de CAS:
1066-45-1
Peso molecular:
199.27
Beilstein/REAXYS Number:
3535111
MDL number:
MFCD00000520
UNSPSC Code:
12352103
PubChem Substance ID:
24863370
NACRES:
NA.22

form

liquid

Quality Level

100

concentration

1.0 M in hexanes

density

0.797 g/mL at 25 °C

SMILES string

C[Sn](C)(C)Cl

InChI

1S/3CH3.ClH.Sn/h3*1H3;1H;/q;;;;+1/p-1

InChI key

KWTSZCJMWHGPOS-UHFFFAOYSA-M

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Application

Trimethyltin chloride solution (1.0 M in hexanes) can be used as a reagent in the synthesis of conjugated polymers based on isoindigo as acceptor and syn- or anti-benzo[1,2-b:5,4-b′]difuran (BDF) as a donor by Stille cross-coupling reaction. It can further be used for the investigation of optical, electrochemical and photovoltaic properties.

Packaging

The 25 mL Sure/Seal™ bottle is recommended as a single-use bottle. Repeated punctures will likely result in decreased performance of product.

Legal Information

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

signalword

Danger

Hazard Classifications

Acute Tox. 1 Dermal - Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Asp. Tox. 1 - Flam. Liq. 2 - Repr. 2 - Skin Irrit. 2 - STOT RE 1 Inhalation - STOT SE 3

target_organs

Central nervous system, Nervous system

Storage Class

3 - Flammable liquids

wgk_germany

WGK 3

flash_point_f

-9.4 °F - closed cup

flash_point_c

-23 °C - closed cup

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Certificados de análisis (COA)

Lot/Batch Number
MKCS2486
MKCS2490
MKCP9053
MKCN7621
SHBJ8521

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Synthesis and photovoltaic properties of new conjugated polymers based on syn-and anti-benzodifuran
Hu C, et al.
Polym. Chem., 3(10), 2949-2955 (2012)
Erwin van Vliet et al.
Neurotoxicology, 28(6), 1136-1146 (2007-08-19)
Neurotoxicity aims to understand how xenobiotics interfere with the function of the nervous system and to unravel their mechanisms of action. Neuronal activity is the primary functional output of the nervous system and deviations from its resting level may indicate
Jiali Cai et al.
Chemical research in toxicology, 22(9), 1582-1587 (2009-08-07)
In evaluating the cytotoxic effects and the mechanisms of the apoptotic and necrotic actions of trimethyltin chloride (TMT) on human hepatoma G2 (HepG2) cells, the present study focused on the involvement of antiproliferation, DNA damage, cell death, apoptosis-related proteins, and
Nguyen Quynh Huong et al.
Biological & pharmaceutical bulletin, 34(12), 1856-1863 (2011-12-02)
The organotin trimethyltin (TMT) is well known to cause neuronal degeneration in the hippocampal dentate gyrus of mice. The first purpose of the present study was to examine whether the cyclooxygenase (COX) inhibitor indomethacin could ameliorate neuronal degeneration in the
Xiaojiang Tang et al.
Toxicology, 271(1-2), 45-50 (2010-03-10)
Trimethyltin chloride (TMT), a byproduct of plastic stabilizers, has caused 67 poisoning accidents in the world; more than 98% (1814/1849) of the affected patients since 1998 have been in China. As a long-established toxic chemical, TMT severely affects the limbic
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