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Merck

Needleless electrospinning with twisted wire spinneret.

Nanotechnology (2014-12-17)
Jani Holopainen, Toni Penttinen, Eero Santala, Mikko Ritala
摘要

A needleless electrospinning setup named 'Needleless Twisted Wire Electrospinning' was developed. The polymer solution is electrospun from the surface of a twisted wire set to a high voltage and collected on a cylindrical collector around the wire. Multiple Taylor cones are simultaneously self-formed on the downward flowing solution. The system is robust and simple with no moving parts aside from the syringe pump used to transport the solution to the top of the wire. The structure and process parameters of the setup and the results on the preparation of polyvinyl pyrrolidone (PVP), hydroxyapatite (HA) and bioglass fibers with the setup are presented. PVP fiber sheets with areas of 40 × 120 cm(2) and masses up to 1.15 g were prepared. High production rates of 5.23 g h(-1) and 1.40 g h(-1) were achieved for PVP and HA respectively. The major limiting factor of the setup is drying of the polymer solution on the wire during the electrospinning process which will eventually force to interrupt the process for cleaning of the wire. Possible solutions to this problem and other ways to develop the setup are discussed. The presented system provides a simple way to increase the production rate and area of fiber sheet as compared with the conventional needle electrospinning.

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原硅酸四乙酯, reagent grade, 98%
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原硅酸四乙酯, ≥99.0% (GC)
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磷酸三乙酯, ReagentPlus®, ≥99.8%
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2-吡咯烷酮, ≥99%
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原硅酸四乙酯, 99.999% trace metals basis
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原硅酸四乙酯, packaged for use in deposition systems
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2-吡咯烷酮, purum, ≥98.0% (GC)
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