推荐产品
蒸汽壓力
24.09 psi ( 55 °C)
6.93 psi ( 20 °C)
品質等級
形狀
liquid
反應適用性
reagent type: catalyst
core: titanium
濃度
0.95-1.10 M NaOH (titration)
1.0 M in methylene chloride
密度
1.365 g/mL at 25 °C
SMILES 字串
Cl[Ti](Cl)(Cl)Cl
InChI
1S/4ClH.Ti/h4*1H;/q;;;;+4/p-4
InChI 密鑰
XJDNKRIXUMDJCW-UHFFFAOYSA-J
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一般說明
氯化钛参与了芳香醛与甲基乙烯基酮的 Baylis-Hillman 反应。使用 pH 值为 2.5 至 6.0 的 TiCl 4 中性溶液（通过添加氧化镁作为基础制备）合成纳米二氧化钛。
應用
通过改良的 Bouveault 反应活化吡咯烷，以改善转化为相应的 α-二甲胺。
訊號詞
Danger
危險分類
Acute Tox. 3 Inhalation - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3
標靶器官
Central nervous system
安全危害
儲存類別代碼
6.1B - Non-combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
水污染物質分類（WGK）
WGK 2
閃點（°F）
Not applicable
閃點（°C）
Not applicable
其他客户在看
Precipitation of nanosized titanium dioxide from aqueous titanium (IV) chloride solutions by neutralization with MgO.
Li Y and Demopoulos GP.
Hydrometallurgy, 90(1), 26-33 (2008)
Titanium(IV) chloride and the amine-promoted baylis-hillman reaction
Shi et al.
Organic letters, 2(23), 3755-3755 (2000-11-14)
Denton, S.M. Wood, A.
Synlett, 55-55 (1999)
Charles Dylan Turner et al.
Organic letters, 14(18), 4970-4973 (2012-09-08)
The Ti(IV)-catalyzed Ugi condensation of α-amino acids with electron-rich aromatic aldehydes performs adequately even with sterically demanding α-amino carboxylate salts. The reaction occurs diastereoselectively, in some cases with virtually complete diastereoselectivity. A stereochemical rationale for the reaction is proposed.
Soji Shimizu et al.
Chemical communications (Cambridge, England), 49(16), 1621-1623 (2013-01-23)
Pyrrolopyrrole aza-BODIPY analogues were synthesized from diketopyrrolopyrrole and heteroaromatic amines in the presence of titanium tetrachloride. These novel compounds exhibit intense absorption in the visible region and strong emission with high fluorescence quantum yields greater than 0.8.
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