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Merck

89610

Sigma-Aldrich

邻甲基苯胺

purum p.a., ≥99.5% (GC)

别名:

2-氨基甲苯, 2-甲基苯胺

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About This Item

线性分子式:
CH3C6H4NH2
CAS号:
分子量:
107.15
Beilstein:
741981
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

3.7 (vs air)

品質等級

蒸汽壓力

0.26 mmHg ( 25 °C)

等級

purum p.a.

化驗

≥99.5% (GC)

形狀

liquid

自燃溫度

899 °F

雜質

≤0.1% water
≤0.5% m- and p-toluidine (GC)

燃燒殘留物

≤0.01% (as SO4)

折射率

n20/D 1.572 (lit.)
n20/D 1.572

bp

199-200 °C (lit.)
89-90 °C/11 mmHg (lit.)

mp

−28 °C (lit.)

溶解度

H2O: slightly soluble

密度

1.008 g/mL at 25 °C (lit.)

正離子痕跡

Ca: ≤5 mg/kg
Cd: ≤1 mg/kg
Co: ≤1 mg/kg
Cr: ≤1 mg/kg
Cu: ≤1 mg/kg
Fe: ≤1 mg/kg
K: ≤20 mg/kg
Mg: ≤1 mg/kg
Mn: ≤1 mg/kg
Na: ≤20 mg/kg
Ni: ≤1 mg/kg
Pb: ≤1 mg/kg
Zn: ≤1 mg/kg

SMILES 字串

Cc1ccccc1N

InChI

1S/C7H9N/c1-6-4-2-3-5-7(6)8/h2-5H,8H2,1H3

InChI 密鑰

RNVCVTLRINQCPJ-UHFFFAOYSA-N

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一般說明

o-Toluidine belongs to the class of monocyclic aromatic amines, which are of research and industrial importance. It can be used as a derivatization agent for the resolution of analytes by the formation of chromophores, which can be visualized by UV radiation or fluorescence.

應用

o-Toluidine may be used as a TLC Visualization (Staining) Reagent for the detection of reducing sugars in protein hydrolysates by using high-performance thin-layer chromatography (HPTLC) coupled with UV diffuse reflectance scanning densitometry.

注意

储存中可能变色

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 2 - Carc. 1B - Eye Irrit. 2

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

185.0 °F - closed cup

閃點(°C)

85 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Determination of aromatic amines in textile after bromination, by gas chromatography coupled with electron capture detection
Dados AE, et al.
Chromatographia, 59(5-6), 335-341 (2004)
An o-toluidine method for detection of carbohydrates in protein hydrolysates
Morcol T and Velander WH
Analytical Biochemistry, 195(1), 153-159 (1991)
Tania Carreón et al.
Occupational and environmental medicine, 67(5), 348-350 (2009-11-04)
In 1991, the US National Institute for Occupational Safety and Health (NIOSH) reported an increased bladder cancer risk in a cohort of 1749 workers potentially exposed to o-toluidine and aniline at a chemical manufacturing plant. As additional information showed that
Hun-Je Jo et al.
Chemosphere, 70(6), 949-957 (2007-09-26)
In this study, major toxicants in pigment wastewaters (i.e. raw wastewater and effluent) were determined by toxicity identification evaluations (TIEs), and changes in their toxicities due to combined gamma-ray (gamma-ray) and ozone treatments were evaluated. From TIE results using Daphnia
Qin Yang et al.
Talanta, 81(1-2), 664-672 (2010-03-02)
The electrochemical synthesis and characterization of a copolymer, poly(o-toluidine-co-o-aminophenol), were conducted using in situ piezoelectric FTIR spectroelectrochemistry. The monomer feed ratio strongly affects the copolymerization rate and the properties of the copolymer during the electrosynthesis in 0.5M H(2)SO(4) aqueous solution.

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