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Merck

648531

Sigma-Aldrich

N,N-二甲基甲酰胺

suitable for HPLC, ≥99.9%

别名:

DMF, NSC 5356

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About This Item

线性分子式:
HCON(CH3)2
CAS号:
分子量:
73.09
Beilstein:
605365
EC號碼:
MDL號碼:
分類程式碼代碼:
12190000
PubChem物質ID:

蒸汽密度

2.5 (vs air)

品質等級

蒸汽壓力

2.7 mmHg ( 20 °C)

化驗

≥99.9%

形狀

liquid

自燃溫度

833 °F

expl. lim.

15.2 %

技術

HPLC: suitable

雜質

≤0.030% water

蒸發殘留物

≤0.0005%

折射率

n20/D 1.430 (lit.)

bp

153 °C (lit.)

mp

−61 °C (lit.)

密度

0.944 g/mL (lit.)

吸收

0.010 at 340 nm
0.010 at 400 nm
0.05 at 310 nm
0.10 at 295 nm
0.30 at 275 nm
1.00 at 270 nm

應用

food and beverages

SMILES 字串

[H]C(=O)N(C)C

InChI

1S/C3H7NO/c1-4(2)3-5/h3H,1-2H3

InChI 密鑰

ZMXDDKWLCZADIW-UHFFFAOYSA-N

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一般說明

N,N-Dimethylformamide (DMF) is the commonly employed solvent for chemical reactions. DMF is a useful solvent employed for the isolation of chlorophyll from plant tissues. It is widely employed reagent in organic synthesis. It plays multiple roles in various reactions such as solvent, dehydrating agent, reducing agent as well as catalyst. It is a multipurpose building block for the synthesis of compounds containing O, -CO, -NMe2, -CONMe2, -Me, -CHO as functional groups. Dielectric relaxation experiments on DMF have been conducted between 238.15K and 338.15K. The thermophysical properties of the molecular interactions between DMF and the ionic liquids, ammonium salts and imidazolium salts have been studied. The characteristics of solute-solvent interactions between ammonium nitrate and DMF have been investigated.

應用

多种疏水性有机化合物的溶剂。

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訊號詞

Danger

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Eye Irrit. 2 - Flam. Liq. 3 - Repr. 1B

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 2

閃點(°F)

135.5 °F - closed cup

閃點(°C)

57.5 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


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Synthesis and electrochemical characterization of aPEO-based polymer electrolytes.
Rodrigues LC, et al.
Journal of Solid State Electrochemistry, 16(4), 1623-1629 (2012)
Measurements and molecular interactions for N,N-dimethylformamide with ionic liquid mixed solvents.
Attri P, et al.
The Journal of Physical Chemistry B, 114(18), 6126-6133 (2010)
The dynamics of liquid formamide, N-methylformamide, N,N-dimethylformamide, and N,N-dimethylacetamide. A dielectric relaxation study.
Barthel J, et al.
Journal of Molecular Liquids, 98, 51-69 (2002)
Volumetric properties of ammonium nitrate in N,N-dimethylformamide.
Vranes M, et al.
The Journal of Chemical Thermodynamics, 54, 245-249 (2012)
W P Inskeep et al.
Plant physiology, 77(2), 483-485 (1985-02-01)
We found inconsistencies in the commonly used data for chlorophyll analysis in 80% acetone. Recently developed extinction coefficients for chlorophyll b in N,N-dimethylformamide (DMF) based on values from 80% acetone are low as a result of these inconsistencies. We determined

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