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Merck

64270

Sigma-Aldrich

甲基磺酰氯

purum, ≥98.0% (AT)

别名:

甲磺酰氯

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About This Item

线性分子式:
CH3SO2Cl
CAS号:
分子量:
114.55
Beilstein:
506297
EC 号:
MDL编号:
UNSPSC代码:
12352101
PubChem化学物质编号:
NACRES:
NA.22

等级

purum

质量水平

方案

≥98.0% (AT)

折射率

n20/D 1.452 (lit.)
n20/D 1.452

沸点

60 °C/21 mmHg (lit.)

密度

1.48 g/mL at 25 °C (lit.)

SMILES字符串

CS(Cl)(=O)=O

InChI

1S/CH3ClO2S/c1-5(2,3)4/h1H3

InChI key

QARBMVPHQWIHKH-UHFFFAOYSA-N

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应用

Methanesulfonyl chloride can be used for the mesylation of primary alcohols to synthesize the corresponding methanesulfonates. It may also be used for the conversion of amines to the corresponding sulfonamides.

象形图

Skull and crossbonesCorrosion

警示用语:

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 3 Oral - Acute Tox. 4 Dermal - Eye Dam. 1 - Met. Corr. 1 - Skin Corr. 1B - Skin Sens. 1 - STOT SE 3

靶器官

Respiratory system

储存分类代码

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

WGK

WGK 2

闪点(°F)

215.6 °F - closed cup

闪点(°C)

102 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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访问文档库

Methanesulfonyl Chloride.
e-EROS Encyclopedia of Reagents for Organic Synthesis (2007)
Water-solvent method for tosylation and mesylation of primary alcohols promoted by KOH and catalytic amines.
Morita J I
Green Chemistry, 7(10), 711-715 (2005)
Methanesulfonyl Chloride.
e-EROS Encyclopedia of Reagents for Organic Synthesis. (2007)
Base-free monosulfonylation of amines using tosyl or mesyl chloride in water
Kamal A
Tetrahedron Letters, 49(2), 348-353 (2008)
Gas-liquid chromatographic determination of residues of methiocarb and its toxic metabolites with the flame photometric detector after derivatization with methanesulfonyl chloride.
J C Maitlen
Journal of agricultural and food chemistry, 29(2), 260-264 (1981-03-01)

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