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Merck

21300

Sigma-Aldrich

(+)-樟脑

purum, natural, ≥97.0% (sum of enantiomers, GC)

别名:

(1R)-(+)-樟脑, (1R)-1,7,7-三甲基二环[2.2.1]庚烷-2-酮

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About This Item

经验公式(希尔记法):
C10H16O
CAS号:
分子量:
152.23
Beilstein:
2042745
EC號碼:
MDL號碼:
分類程式碼代碼:
12352115
PubChem物質ID:

等級

purum

化驗

≥97.0% (sum of enantiomers, GC)

光學活性

[α]20/D +42.5±2.5°, c = 10% in ethanol

品質

natural

mp

176-180 °C

SMILES 字串

[H][C@@]12CC[C@@](C)(C(=O)C1)C2(C)C

InChI

1S/C10H16O/c1-9(2)7-4-5-10(9,3)8(11)6-7/h7H,4-6H2,1-3H3/t7-,10+/m1/s1

InChI 密鑰

DSSYKIVIOFKYAU-XCBNKYQSSA-N

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其他說明

(+)-樟脑是手性池化合物,广泛作为手性结构单元;已用于立体选择性制备许多天然产物:大量含有降莰烷骨架的化合物和其他化合物

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产品编号
说明
价格

訊號詞

Danger

危險分類

Acute Tox. 4 Inhalation - Eye Dam. 1 - Flam. Sol. 2 - Skin Irrit. 2 - STOT SE 2 Inhalation

標靶器官

Lungs

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 1

閃點(°F)

147.2 °F - closed cup

閃點(°C)

64 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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I. Kitagawa et al.
Chemical & Pharmaceutical Bulletin, 32, 1294-1294 (1984)
Weiling Wang et al.
FASEB journal : official publication of the Federation of American Societies for Experimental Biology, 33(5), 6185-6196 (2019-02-16)
Human autosomal dominant polycystic kidney disease (ADPKD) is characterized by bilateral renal cysts that lead to a decline in kidney function. Previous studies reported aquaporin (AQP)-3 expression in cysts derived from collecting ducts in ADPKD. To study the role of
J.H. Hutchinson et al.
Canadian Journal of Chemistry, 65, 1-1 (1987)
Christian Merten et al.
The journal of physical chemistry. A, 116(27), 7329-7336 (2012-06-06)
In the present work, the first observation of strong resonance Raman optical activity (RROA) involving more that one resonant electronic state is reported. The chiral transition metal complex bis-(trifluoroacetylcamphorato) copper(II), abbreviated Cu(tfc)(2), exhibits both resonance Raman (RR) and RROA spectra
Hiroyuki Yamashita et al.
Pharmaceutical research, 30(1), 70-80 (2012-08-22)
Although a number of studies have reported that cocrystals can form by heating a physical mixture of two components, details surrounding heat-induced cocrystal formation remain unclear. Here, we attempted to clarify the thermal behavior of a physical mixture and cocrystal

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