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Merck

04004

Sigma-Aldrich

红磷

≥97.0%

别名:

P

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About This Item

经验公式(希尔记法):
P
CAS号:
分子量:
30.97
EC號碼:
MDL號碼:
分類程式碼代碼:
12141909
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

0.02 (vs air)

品質等級

蒸汽壓力

0.03 mmHg ( 21 °C)
1 mmHg ( 76.6 °C)

化驗

≥97.0%

自燃溫度

500 °F

反應適用性

reaction type: Buchwald-Hartwig Cross Coupling Reaction
reaction type: Heck Reaction
reaction type: Hiyama Coupling
reaction type: Negishi Coupling
reaction type: Sonogashira Coupling
reaction type: Stille Coupling
reaction type: Suzuki-Miyaura Coupling
reagent type: catalyst

電阻係數

10 μΩ-cm, 20°C

mp

416 °C (subl.) (lit.)

密度

2.34 g/mL at 25 °C (lit.)

正離子痕跡

Fe: ≤2000 mg/kg

儲存溫度

room temp

SMILES 字串

[P]

InChI

1S/P

InChI 密鑰

OAICVXFJPJFONN-UHFFFAOYSA-N

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一般說明

Red phosphorus is the most common allotrope ofphosphorus due to its relative stability compared to white phosphorus. It has a variety of uses including, but notlimited to, use as a catalyst, battery anode, flame retardant, and igniter.

應用

Red phosphorus can be used as a:
  • Photocatalyst for the formation of H2 from water.
  • Catalyst in the synthesis of tris(2-pyridyl)phosphine by reacting with 2-bromopyridine in the presence of a base.
  • Flame retardant along with aluminum oxide in recycled poly(ethylene terephthalate).
  • Anode material in combination with carbon composites for sodium-ion batteries.

象形圖

Flame

訊號詞

Warning

危險聲明

危險分類

Aquatic Chronic 3 - Flam. Sol. 2

儲存類別代碼

4.1B - Flammable solid hazardous materials

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

Lot/Batch Number

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其他客户在看

Red phosphorus: an elemental photocatalyst for hydrogen formation from water
Wang F, et al.
Applied Catalysis. B, Environmental, 111, 409-414 (2012)
Expedient one-pot organometallics-free synthesis of tris (2-pyridyl) phosphine from 2-bromopyridine and elemental phosphorus
Trofimov BA, et al.
Tetrahedron Letters, 53(19), 2424-2427 (2012)
New Evidence Concerning the Structure of Amorphous Red Phosphorus
Hartl H
Angewandte Chemie (International Edition in English), 34(23-24), 2637-2638 (1996)
Special materials in pyrotechnics: V. Military applications of phosphorus and its compounds
Koch E-C
Propellants, Explosives, Pyrotechnics, 33(3), 165-176 (2008)
Red phosphorus/aluminium oxide compositions as flame retardants in recycled poly (ethylene terephthalate
Laoutid F, et al.
Polymer Degradation and Stability, 82(2), 357-363 (2003)

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