跳转至内容
Merck
所有图片(1)

文件

8.06722

Sigma-Aldrich

Nickel(II) chloride

anhydrous for synthesis

别名:

Nickel(II) chloride, Nickel dichloride

登录查看公司和协议定价
所有图片(1)

About This Item

经验公式（希尔记法）:
Cl2Ni
CAS号:
7718-54-9
分子量:
129.60
分類程式碼代碼:
12352302
酶委員會索引編號:
231-743-0
NACRES:
NA.22

蒸汽壓力

1.33 hPa ( 671 °C)

品質等級

200

形狀

powder

效力

105 mg/kg LD50, oral (Rat)

pH值

4 (20 °C, 500 g/L in H2O)

mp

1009 °C

密度

3.55 g/cm3

儲存溫度

2-30°C

InChI

1S/2ClH.Ni/h2*1H;/q;;+2/p-2

InChI 密鑰

QMMRZOWCJAIUJA-UHFFFAOYSA-L

應用

Nickel(II) chloride can be used as a catalyst:
  • To synthesize acyclic and cyclic dithioacetals via thioacetalization of aldehydes.
  • To prepare α-aminonitrile derivatives via a one-pot, three-component coupling reaction of aldehydes, amines, and trimethylsilyl cyanide.
  • In the hydrodefluorination of fluoroarenes in the presence of lithium triethylborohydride.

分析報告

Assay (complexometric): 98.0 - 102.0 %
Loss on drying (150 °C; 3h): ≤ 1.0 %

訊號詞

Danger

危險分類

Acute Tox. 3 Inhalation - Acute Tox. 3 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Carc. 1A Inhalation - Muta. 2 - Repr. 1B - Resp. Sens. 1 - Skin Irrit. 2 - Skin Sens. 1 - STOT RE 1 Inhalation

標靶器官

Lungs

儲存類別代碼

6.1D - Non-combustible, acute toxic Cat.3 / toxic hazardous materials or hazardous materials causing chronic effects

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

输入产品批号来搜索 分析证书(COA) 。批号可以在产品标签上"批“ （Lot或Batch）字后找到。

已有该产品？

在文件库中查找您最近购买产品的文档。

访问文档库

Nickel (II) chloride as an efficient and useful catalyst for chemoselective thioacetalization of aldehydes
Khan AT, et al.
Tetrahedron Letters, 44(5), 919-922 (2003)
Highly Efficient Nickel (II) Chloride/Bis (tricyclohexylphosphine) nickel (II) Chloride-Cocatalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride
Zhao Wenwen, et al.
advanced synthesis and catalysis, 354(4), 574-578 (2012)
Highly Efficient Nickel (II) Chloride/Bis (tricyclohexylphosphine) nickel (II) Chloride-Cocatalyzed Hydrodefluorination of Fluoroarenes and Trifluorotoluenes with Superhydride
Zhao Wenwen, et al.
Advanced Synthesis & Catalysis, 354(4), 574-578 (2012)
Nickel (II) chloride catalyzed one-pot synthesis of α-aminonitriles
De Surya Kanta
J. Mol. Catal. A: Chem., 225(2), 169-171 (2005)

我们的科学家团队拥有各种研究领域经验，包括生命科学、材料科学、化学合成、色谱、分析及许多其他领域.

联系技术服务部门