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Merck

T7394

Sigma-Aldrich

N,N,N′,N′-四甲基对苯二胺

99%, powder

别名:

TMPD, TMPDA, TMPPD, Wurster 试剂

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About This Item

线性分子式:
C6H4[N(CH3)2]2
分子量:
164.25
Beilstein:
1564025
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

99%

形狀

flakes
powder

顏色

off-white to brown

bp

260 °C (lit.)

mp

49-51 °C (lit.)

SMILES 字串

CN(C)c1ccc(cc1)N(C)C

InChI

1S/C10H16N2/c1-11(2)9-5-7-10(8-6-9)12(3)4/h5-8H,1-4H3

InChI 密鑰

CJAOGUFAAWZWNI-UHFFFAOYSA-N

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一般說明

N,N,N′,N′-四甲基对苯二胺(TMPDA)是一种低电离电位的氧化还原试剂,广泛用作光系统I的电子供体。它还可用作光系统II的电子受体。

應用

N,N,N′,N′-四甲基对苯二胺(TMPDA)可用于:
  • 过氧苯甲酰的流动注射分析。
  • 研究其到卤化溶剂的光致电子转移。

注意

储存中颜色可能变深。

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Acute Tox. 4 Dermal - Acute Tox. 4 Inhalation - Acute Tox. 4 Oral

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 1

閃點(°F)

230.0 °F - closed cup

閃點(°C)

110 °C - closed cup


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Flow injection analysis of benzoyl peroxide using N, N, N, N-tetramethyl-p-phenylenediamine (TMPDA) and surfactants
Pharr DY & Tomsyck JA
Analytical Letters, 42(5), 821-832 (2009)
Interaction of N, N, N′ ,N′ -tetramethyl-p-phenylenediamine with photosystem II as revealed by thermoluminescence: reduction of the higher oxidation states of the Mn cluster and displacement of plastoquinone from the QB niche
Gauthier A, et al.
Biochimica et Biophysica Acta, 1757(11), 1547-1556 (2006)
Ultrafast photoinduced electron transfer from N, N, N′ , N′ -tetramethyl-p-phenylenediamine and N, N, N′ , N′ -tetramethylbenzidine to dichloromethane
Boilet L, et al.
Journal of Photochemistry and Photobiology A: Chemistry, 163(3), 529-536 (2004)
Toshiaki Miura
Chemico-biological interactions, 236, 67-73 (2015-04-30)
To investigate the mechanisms of cardiotoxicity induced by adriamycin (ADM), the enzymatic activities of ADM-Fe(3+), including the peroxidase and lipoxygenase (LOX) activity, and participation of active oxygen species in the damage to biological components were examined. ADM-Fe(3+), but not ADM
P P Bawol et al.
Physical chemistry chemical physics : PCCP, 20(33), 21447-21456 (2018-08-09)
The reversibility of current Li-O2 batteries suffers from high charging overpotentials. To address this problem, the use of redox mediators has been proposed, which are supposed to improve the sluggish reaction kinetics of the oxygen evolution reaction via a solution

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