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Merck
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文件

O9328

Sigma-Aldrich

草酰胺

98%

别名:

乙二酰二胺

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About This Item

线性分子式:
NH2COCONH2
CAS号:
471-46-5
分子量:
88.07
Beilstein:
1743262
EC號碼:
207-442-5
MDL號碼:
MFCD00008007
分類程式碼代碼:
12352100
PubChem物質ID:
24898068
NACRES:
NA.22

品質等級

100

化驗

98%

形狀

powder

mp

>300 °C (lit.)

SMILES 字串

NC(=O)C(N)=O

InChI

1S/C2H4N2O2/c3-1(5)2(4)6/h(H2,3,5)(H2,4,6)

InChI 密鑰

YIKSCQDJHCMVMK-UHFFFAOYSA-N

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相关类别

應用

草酰胺可用于：
  • 作为合成例如双（苯并咪唑）和通过与糠醛进行水缩合形成的席夫碱配体的前体。
  • 通过与尿素自组装聚合形成碳氮化物（g-C3N4）纳米管。
  • 作为合成双核 IrIII配合物[Ir2(μ2-恶酰胺基-N,N′,O,O′)(ptpy)4]的桥联配体，ptpy=2-（对甲苯基）吡啶基。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H302,H315,H319

危險分類

Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2

儲存類別代碼

11 - Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

dust mask type N95 (US), Eyeshields, Gloves

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Journal of Molecular Structure, 1176, 366-375 (2019)
E Armelin et al.
The Journal of organic chemistry, 66(24), 8076-8085 (2001-11-28)
The conformational properties of the oxalamide group and crystal structure of several polyoxalamides have been investigated by computational methods. First, a detailed quantum mechanical study of the conformational preferences of N,N'-dimethyloxalamide is reported. Results, which were obtained at the MP2/6-31G(d)
Li-Na Zhu et al.
Inorganic chemistry, 46(4), 1297-1304 (2007-01-25)
Four heteronuclear complexes Mn(CuL)2(SCN)2 (1), {[Mn(CuL)2(mu-dca)2].2H2O}n (2), Zn(CuL)2(SCN)2 (3), and [Fe(CuL)(N3)2]2 (4) incorporating macrocyclic oxamide ligands have been synthesized and structurally characterized. L is the dianion of diethyl 5,6,7,8,15,16-hexahydro-6,7-dioxodibenzo[1,4,8,11]-tetraazacyclotetradecine-13,18-dicarboxylate, and dca is the dicyanamide. The structure of 1 or 3
Synthesis and Molecular Structure of the New Green Emitting Complex [Ir2(?2-oxamidato-N, N?, O, O?)(2-(p-tolyl)pyridinato)4]
Graf M, et al.
Zeitschrift fur Anorganische und Allgemeine Chemie, 639(7), 1090-1094 (2013)
Sergey P Gavrish et al.
Dalton transactions (Cambridge, England : 2003), (41)(41), 4708-4714 (2007-10-18)
A comparison of the molecular structure of related nickel(II) complexes of the open-chain and 13-membered macrocyclic oxamide-derived ligands NiL(1).4H2O and NiL(2).3H2O revealed that the formation of an additional 6-membered chelate ring in the complex results in rather small changes in
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