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Merck
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M72609

Sigma-Aldrich

N-甲基哌啶

99%

别名:

1-甲基哌啶

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About This Item

经验公式（希尔记法）:
C6H13N
CAS号:
626-67-5
分子量:
99.17
Beilstein:
1073
EC 号:
210-959-9
MDL编号:
MFCD00006491
UNSPSC代码:
12352100
PubChem化学物质编号:
24897150
NACRES:
NA.22

质量水平

200

方案

99%

折射率

n20/D 1.4378 (lit.)

沸点

106-107 °C (lit.)

密度

0.816 g/mL at 25 °C (lit.)

SMILES字符串

CN1CCCCC1

InChI

1S/C6H13N/c1-7-5-3-2-4-6-7/h2-6H2,1H3

InChI key

PAMIQIKDUOTOBW-UHFFFAOYSA-N

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相关类别

应用

反应物用于：
  • sp3 C-H 键通过钌 (II) 催化剂与环胺 C (3) 烷基化反应活化
  • Z-肉桂酸的一锅法合成

用于合成以下物质的反应物：
  • 不对称尿素酶
  • 抗菌咪唑、吡咯烷和哌啶盐
  • 通过钯催化的有机锡硫代酯偶联反应，得到角化酶A的C1-C16片段
  • 胰岛素样生长因子-1 受体和 ErbB 家族受体激酶的多靶点抑制剂

警示用语：

Danger

危险分类

Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Acute Tox. 4 Oral - Aquatic Chronic 3 - Eye Dam. 1 - Flam. Liq. 2 - Skin Corr. 1B

储存分类代码

3 - Flammable liquids

WGK

WGK 2

闪点(°F)

37.4 °F - closed cup

闪点(°C)

3 °C - closed cup

个人防护装备

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
SDBB1572
STBL3379
STBL4355
STBK7924
STBK9940

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Xuenan Li et al.
Journal of food science, 85(9), 2754-2761 (2020-08-15)
N,N-dimethylpiperidinium (mepiquat) is a new process-induced compound formed from natural constituents during the cooking process. Mepiquat was first found in coffee and cereal products, but its formation mechanism in coffee is still unclear. In the current study, Arabica and Robusta
Oscar B Torres et al.
Analytical and bioanalytical chemistry, 410(16), 3885-3903 (2018-04-21)
We describe for the first time a method that utilizes microscale thermophoresis (MST) technology to determine polyclonal antibody affinities to small molecules. Using a novel type of heterologous MST, we have accurately measured a solution-based binding affinity of serum antibodies
[The mechanism of reverse inhibition of cholinesterases by thionphosphonates].
N N Kovalev et al.
Izvestiia Akademii nauk SSSR. Seriia biologicheskaia, (6)(6), 926-929 (1988-11-01)
Francisc Potmischil et al.
Magnetic resonance in chemistry : MRC, 45(3), 231-235 (2007-01-16)
The (15)N chemical shifts of 13 N-methylpiperidine-derived mono-, bi- and tricycloaliphatic tertiary amines, their methiodides and their N-epimeric pairs of N-oxides were measured, and the contributions of specific structural parameters to the chemical shifts were determined by multilinear regression analysis.
A Kolocouris et al.
The Journal of organic chemistry, 66(15), 4989-4997 (2001-07-21)
When a 1-adamantyl or a 2-adamantyl substituent is introduced at the 2-position in N-methylpiperidine, four different chair conformations are possible. Experimental observation using dynamic NMR spectroscopy and molecular mechanics calculations agree that the chair conformation with an equatorial adamantyl group
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