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品質等級
化驗
96%
形狀
liquid
折射率
n20/D 1.398 (lit.)
bp
125 °C (lit.)
密度
0.854 g/mL at 25 °C (lit.)
SMILES 字串
CCOC(OCC)C=C
InChI
1S/C7H14O2/c1-4-7(8-5-2)9-6-3/h4,7H,1,5-6H2,2-3H3
InChI 密鑰
MCIPQLOKVXSHTD-UHFFFAOYSA-N
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應用
丙烯醛二乙基缩醛广泛用于进行化学选择性 Heck 芳基化,合成 3-芳基丙酸酯或肉桂醛衍生物。
它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。
它也可用作合成天然产物如 (-)-(Z)-脱氧普卡灵、(-)-Laulimalide、botryodiplodin、neolaulimalide 和 isolaulimalide 的前体之一。
訊號詞
Danger
危險聲明
危險分類
Eye Irrit. 2 - Flam. Liq. 2
儲存類別代碼
3 - Flammable liquids
水污染物質分類(WGK)
WGK 3
閃點(°F)
59.0 °F - closed cup
閃點(°C)
15 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Synthesis of (-)?(Z)?Deoxypukalide.
Angewandte Chemie (International Edition in English), 47(38), 7314-7316 (2008)
Acrolein Diethyl Acetal: A Three?Carbon Homologating Reagent for the Synthesis of β?Arylpropanoates and Cinnamaldehydes by Heck Reaction Catalyzed by a Kaiser Oxime Resin Derived Palladacycle.
The Journal of Organic Chemistry, 2008(18), 3102-3106 (2008)
Plant & cell physiology, 61(5), 967-977 (2020-03-08)
Myrosinase (β-thioglucoside glucohydrolase, enzyme nomenclature, EC 3.2.1.147, TGG) is a highly abundant protein in Arabidopsis guard cells, of which TGG1 and TGG2 function redundantly in abscisic acid (ABA)- and methyl jasmonate-induced stomatal closure. Reactive carbonyl species (RCS) are α,β-unsaturated aldehydes
An efficient palladium-catalyzed synthesis of cinnamaldehydes from acrolein diethyl acetal and aryl iodides and bromides.
Organic Letters, 5(5), 777-780 (2003)
Organic & biomolecular chemistry, 15(4), 884-893 (2017-01-04)
As part of our ongoing work on the synthesis of a new class of plant hormones named Strigolactones (SLs) and their analogues, we became interested in tracing bioactive molecules with red emitting BODIPY fluorophores in order to unravel signaling and
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