86652

四乙基高碘酸铵

technical, moistened with water, ≥90% (calc. based on dry substance, RT)

• 别名: N,N,N-Triethylethanaminium salt with periodic acid
• 线性分子式: (C₂H₅)₄N(IO₄)
• CAS号: 5492-69-3
• 分子量: 321.15
• Beilstein: 4166132
• EC號碼: 226-824-2
• MDL號碼: MFCD00043182
• 分類程式碼代碼: 12352000
• PubChem物質ID: 57653063
• NACRES: NA.22

属性

• 等級: technical
• 化驗: ≥90% (calc. based on dry substance, RT)
• 形狀: crystals
• 品質: moistened with water
• 包含: ~10% water as stabilizer
• 反應適用性: reagent type: oxidant
• mp: ~170 °C (dec.)
• SMILES 字串: [O-]I(=O)(=O)=O.CC[N+](CC)(CC)CC
• InChI: 1S/C8H20N.HIO4/c1-5-9(6-2,7-3)8-4;2-1(3,4)5/h5-8H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
• InChI 密鑰: YXYPONURGKGPDV-UHFFFAOYSA-M

说明

應用

Reactant for intramolecular cycloaddition reactions

Tetraethylammonium (meta)periodate can be used as an oxidant in the N-dealkylation of tertiary amines using Fe(III) complex as a catalyst. It can also be employed as a reagent in the intramolecular cycloaddition reactions.

其他說明

在有机溶剂中使用的氧化剂；1,2-二醇和烯烃类化合物的氧化

安全信息

• 象形圖: GHS02
• 訊號詞: Danger
• 危險聲明: H228
• 防範說明: P210
• 危險分類: Flam. Sol. 1
• 儲存類別代碼: 4.1B - Flammable solid hazardous materials
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Gloves, type N95 (US)