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791806

4-氨基-2,3,5,6-四氟三氟甲苯

Name: 4-氨基-2,3,5,6-四氟三氟甲苯
Brand: ALDRICH

97%

别名:

2,3,5,6-四氟-4-三氟甲基苯胺

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About This Item

线性分子式:

CF₃C₆F₄NH₂

CAS号:

651-83-2

分子量:

233.09

Beilstein:

2657893

MDL號碼:

MFCD00091518

分類程式碼代碼:

12352101

PubChem物質ID:

329768293

NACRES:

NA.22

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Sigma-Aldrich

ALD00606

Wang−Yu non-directed C−H functionalization ligand

Sigma-Aldrich

103713

2,3,4,5,6-五氟苯胺

Sigma-Aldrich

765120

(1-芘)甲基丙烯酸甲酯

Sigma-Aldrich

ALD00004

Li-Yu t-Butyl Quinoline

Sigma-Aldrich

ALD00508

Yu Fluorination Ligand

Sigma-Aldrich

773360

Poly(2-ethyl-2-oxazoline) α-methyl, ω-2-hydroxyethylamine terminated

Sigma-Aldrich

359688

Boc-Lys-OH

Sigma-Aldrich

224936

4-(三氟甲基)苯胺

Sigma-Aldrich

795283

Poly(2-methyl-2-oxazoline), hydroxy terminated

Sigma-Aldrich

193135

3,5-二(三氟甲基)苯胺

化驗

97%

形狀

liquid

反應適用性

reaction type: C-C Bond Formation
reagent type: catalyst
reaction type: C-H Activation

折射率

n20/D 1.431 (lit.)
n20/D 1.432

bp

186 °C (lit.)

密度

1.662 g/mL at 25 °C
1.687 g/mL at 25 °C (lit.)

SMILES 字串

Nc1c(F)c(F)c(c(F)c1F)C(F)(F)F

InChI

1S/C7H2F7N/c8-2-1(7(12,13)14)3(9)5(11)6(15)4(2)10/h15H2

InChI 密鑰

FJOACTZFMHZHSC-UHFFFAOYSA-N

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其他說明

Acidic amides are superior directing groups for promoting C-H activation reactions with both Pd(0)/PR₃ and Pd(II) catalysts.

Used in the Preparation of

Lactams via palladium-catalyzed olefination of arylamides with benzylacrylate, followed by 1,4-conjugate addition
N-(fluorinated aryl)benzamides as substrates for regioselective C-H amination reactions with O-benzoylhydroxylamines
Substituted succinimides via palladium-catalyzed carbonylation of N-aryl amides
N-aryl cyclopropanecarboxamide substrates and various amino acid ligands for palladium-catalyzed C-H activation of cyclopropanes

ALD00600

Zhu-Yu Auxiliary, 98%

象形圖

GHS07

訊號詞

Warning

危險聲明

H315,H319,H335

防範說明

P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

分析证书(COA)

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Wasa, M;

Journal of the American Chemical Society, 132(11), 3680-3681 null

Pd(II)-catalyzed carbonylation of C(sp3)-H bonds: a new entry to 1,4-dicarbonyl compounds.

Eun Jeong Yoo et al.

Journal of the American Chemical Society, 132(49), 17378-17380 (2010-11-19)

Pd(II)-catalyzed β-C(sp(3))-H carbonylation of N-arylamides under CO (1 atm) has been achieved. Following amide-directed C(sp(3))-H cleavage and insertion of CO into the resulting [Pd(II)-C(sp(3))] bond, intramolecular C-N reductive elimination gave the corresponding succinimides, which could be readily converted to 1,4-dicarbonyl

Palladium(0)-Catalyzed Alkynylation of C(sp³)-H Bonds

He, J.:

Journal of the American Chemical Society null

Pd-catalyzed intermolecular C-H amination with alkylamines.

Eun Jeong Yoo et al.

Journal of the American Chemical Society, 133(20), 7652-7655 (2011-04-28)

C-H amination of N-aryl benzamides with O-benzoyl hydroxylamines has been achieved with either Pd(II) or Pd(0) catalysts. Furthermore, we demonstrate that secondary amines can be directly used with benzoyl peroxide in a one-pot procedure that proceeds via the in situ

Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes.

Masayuki Wasa et al.

Journal of the American Chemical Society, 133(49), 19598-19601 (2011-11-09)

Systematic ligand development has led to the identification of novel mono-N-protected amino acid ligands for Pd(II)-catalyzed enantioselective C-H activation of cyclopropanes. A diverse range of organoboron reagents can be used as coupling partners, and the reaction proceeds under mild conditions.

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4-氨基-2,3,5,6-四氟三氟甲苯