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Merck

754730

Sigma-Aldrich

三(2,2′-联吡啶)钌(II)六氟磷酸盐

97%

别名:

Ru(bpy)3(PF6)2, 钌-三(2,2′-联吡啶)二六氟磷酸盐

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About This Item

经验公式(希尔记法):
C30H24F12N6P2Ru
CAS号:
分子量:
859.55
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.23

化驗

97%

形狀

solid

反應適用性

core: ruthenium
reaction type: Photocatalysis
reagent type: catalyst

雜質

(Material is not fluorescence active.)

mp

>300 °C

活化光觸媒

425 nm

吸收

13,400 at 456 nm
80,000 at 291 nm

SMILES 字串

[Ru++].F[P-](F)(F)(F)(F)F.F[P-](F)(F)(F)(F)F.c1ccc(nc1)-c2ccccn2.c3ccc(nc3)-c4ccccn4.c5ccc(nc5)-c6ccccn6

InChI

1S/3C10H8N2.2F6P.Ru/c3*1-3-7-11-9(5-1)10-6-2-4-8-12-10;2*1-7(2,3,4,5)6;/h3*1-8H;;;/q;;;2*-1;+2

InChI 密鑰

KLDYQWXVZLHTKT-UHFFFAOYSA-N

相关类别

一般說明

三(2,2′-联吡啶)钌二(六氟磷酸)盐 (Ru(bpy)3(PF6)2)是一种导电聚合物,主要用作电化学器件中的活性层。它可促进高效低压器件形成。这种材料在3V时呈现了0.35和cd/m2的外部量子效率。

應用

Ru(bpy)3(PF6)2可用作共轭聚合物,用于开发基于发光电化学电池的器件,如发光二极管(LED)。它还被用作OLED/传感器研究的高效三重态发射极。

产品可与我们的光反应器系列一起使用:包括Penn PhD(Z744035)& SynLED 2.0 (Z744080

相關產品

产品编号
说明
价格

儲存類別代碼

11 - Combustible Solids

水污染物質分類(WGK)

WGK 3

閃點(°F)

Not applicable

閃點(°C)

Not applicable


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Thin-film solid-state electroluminescent devices based on tris (2, 2 `-bipyridine) ruthenium (II) complexes
Buda, M
Journal of the American Chemical Society, 124(21), 6090-6098 (2002)
Single layer light-emitting devices with high efficiency and long lifetime based on tris (2, 2? bipyridyl) ruthenium (II) hexafluorophosphate
Rudmann H and Rubner MF
Journal of Applied Physics, 90(9), 4338-4345 (2001)
Silvia Voci et al.
Analytical and bioanalytical chemistry, 412(17), 4067-4075 (2020-04-29)
Nanofluidic electrochemical devices confine the volume of chemical reactions to femtoliters. When employed for light generation by electrochemiluminescence (ECL), nanofluidic confinement yields enhanced intensity and robust luminescence. Here, we investigate different ECL pathways, namely coreactant and annihilation ECL in a
Valentina Leandri et al.
Chemphyschem : a European journal of chemical physics and physical chemistry, 20(4), 618-626 (2019-01-10)
The excited state dynamics of Tris(2,2'-bipyridine)ruthenium(II) hexafluorophosphate, [Ru(bpy)3 (PF6 )2 ], was investigated on the surface of bare and sensitized TiO2 and ZrO2 films. The organic dyes LEG4 and MKA253 were selected as sensitizers. A Stern-Volmer plot of LEG4-sensitized TiO2
Direct measurement of the electric-field distribution in a light-emitting electrochemical cell
Slinker JD, et al.
Testing, 6(11), 894-894 (2007)

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