694746

双(3,5-二(三氟甲基)苯基)氯膦

• 别名: P,P-Bis[3,5-bis(trifluoromethyl)phenyl]phosphinous chloride
• 经验公式（希尔记法）: C₁₆H₆ClF₁₂P
• CAS号: 142421-57-6
• 分子量: 492.63
• MDL號碼: MFCD01630852
• 分類程式碼代碼: 12352002
• PubChem物質ID: 329761683
• NACRES: NA.22

属性

• 形狀: solid
• 反應適用性: reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: ligand
• mp: 25-29 °C
• 官能基: phosphine
• SMILES 字串: FC(F)(F)c1cc(cc(c1)C(F)(F)F)P(Cl)c2cc(cc(c2)C(F)(F)F)C(F)(F)F
• InChI: 1S/C16H6ClF12P/c17-30(11-3-7(13(18,19)20)1-8(4-11)14(21,22)23)12-5-9(15(24,25)26)2-10(6-12)16(27,28)29/h1-6H
• InChI 密鑰: DFZQEHBNAJGDCT-UHFFFAOYSA-N

说明

應用

Reactant for synthesis of:

• Chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation
• Ligands for palladium-catalyzed stereoselective allylation reactions
• Ligands for enantioselective hydrogenations
• Josiphos analog as catalyst for asymmetric hydrogenation
• Ligands used in asymmetric hydrovinylation reactions

Reactant for enantioselective hydrogenation reactions catalyzed by Ru-(phosphine-oxazoline) complexes

安全信息

• 象形圖: GHS02,GHS05
• 訊號詞: Danger
• 危險聲明: H261,H314
• 防範說明: P231 + P232 - P280 - P305 + P351 + P338 - P310 - P422
• 危險分類: Skin Corr. 1B - Water-react 3
• 儲存類別代碼: 4.3 - Hazardous materials which set free flammable gases upon contact with water
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type P3 (EN 143) respirator cartridges