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Merck
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文件

693537

Sigma-Aldrich

R-MOP

≥94%

别名:

(R)-(+)-2-(二苯基膦)-2′-甲氧基-1,1′-联萘

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About This Item

经验公式（希尔记法）:
C33H25OP
CAS号:
145964-33-6
分子量:
468.52
MDL號碼:
MFCD00269686
分類程式碼代碼:
12352005
PubChem物質ID:
329761598

化驗

≥94%

形狀

solid

光學活性

[α]20/D +94°, c = 0.5 in chloroform

SMILES 字串

COc1ccc2ccccc2c1-c3c(ccc4ccccc34)P(c5ccccc5)c6ccccc6

InChI

1S/C33H25OP/c1-34-30-22-20-24-12-8-10-18-28(24)32(30)33-29-19-11-9-13-25(29)21-23-31(33)35(26-14-4-2-5-15-26)27-16-6-3-7-17-27/h2-23H,1H3

InChI 密鑰

KRWTWSSMURUMDE-UHFFFAOYSA-N

一般說明

R-MOP是以双萘为主链的膦配体。

應用

用于不对称反应的Takasago配体和复合物

配体用于钯催化烯烃的不对称硅氢化反应 、钯催化烯丙基酯的还原反应 、铑催化的不对称加成反应 和铜 (Ⅰ) 配合物催化的不对称胺化反应 。

法律資訊

与 Takasago 联合销售，仅供研究之用。US5231202

儲存類別代碼

13 - Non Combustible Solids

水污染物質分類（WGK）

WGK 3

閃點（°F）

Not applicable

閃點（°C）

Not applicable

個人防護裝備

Eyeshields, Gloves, type N95 (US)

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The synthesis of P-stereogenic MOP analogues and their use in rhodium catalyzed asymmetric addition
Clarke, E. F.; et al.
Journal of Organometallic Chemistry, 696, 3608-3615 (2011)
A new optically active monodentate phosphine ligand, (R)-(+)-3-diphenylphosphino-3'-methoxy-4,4'-biphenanthryl (MOP-phen): preparation and use for palladium-catalyzed asymmetric reduction of allylic esters with formic acid
Hayashi, T.
Synthesis, 526-532 (1994)
Uozomi, Y.
Journal of the American Chemical Society, 9887-9887 (1991)
Rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to isatins.
Ryo Shintani et al.
Angewandte Chemie (International ed. in English), 45(20), 3353-3356 (2006-04-06)
T Hayashi
Accounts of chemical research, 33(6), 354-362 (2000-07-13)
Chiral monophosphines, whose chirality is due to biaryl axial chirality, have been prepared from enantiomerically pure 2, 2'-dihydroxy-1,1'-binaphthyl and demonstrated to be highly efficient chiral ligands for transition-metal-catalyzed organic transformations, especially for reactions where chelating bisphosphine ligands cannot be used.
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