683981

(5aS,10bR)-5a,10b-二氢-2-(2,4,6-三甲苯基)-4H, 6H-茚并[2,1-b]-1,2,4-三唑并[4,3-d]-1,4-噁嗪鎓氯化物

97%

• 别名: Bode 催化剂 1
• 经验公式（希尔记法）: C₂₁H₂₂ClN₃O · H₂O
• 分子量: 385.89
• UNSPSC代码: 12352005
• PubChem化学物质编号: 329760887

属性

• 方案: 97%
• 表单: solid
• 旋光性: [α]20/D -156.0°, c = 1 in chloroform
• mp: 212-216 °C
• 官能团: ether
• SMILES字符串: [Cl-].Cc1cc(C)c(c(C)c1)-[n+]2c[n@H]3[C@H]4[C@H](Cc5ccccc45)OCc3n2
• InChI: 1S/C21H22N3O.ClH/c1-13-8-14(2)20(15(3)9-13)24-12-23-19(22-24)11-25-18-10-16-6-4-5-7-17(16)21(18)23;/h4-9,12,18,21H,10-11H2,1-3H3;1H/q+1;/p-1/t18-,21+;/m0./s1
• InChI key: GUECWMLEUCWYOS-OZYANKIXSA-M

说明

应用

(5aS,10bR)-5a,10b-Dihydro-2-(2,4,6-trimethylphenyl)-4H, 6H-indeno[2,1-b]-1,2,4-triazolo[4,3-d]-1,4-oxazinium chloride monohydrate can be used as an N-heterocyclic carbene (NHC) organocatalyst:

• In the synthesis of tricyclic β-lactones by reacting 2-bromoenals with 1,3-diketones.
• To functionalize the C2-position of 3-aminobenzofurans using 2-bromoenals as coupling partners.
• In the synthesis of dihydroquinoxalines from substituted bisimines.
• In the preparation of spiro-glutarimide derivatives by reacting cyclic β-ketoamides with α,β-unsaturated aldehydes.

法律信息

与 BioBlocks, Inc. 联合销售

安全信息

• 储存分类代码: 13 - Non Combustible Solids
• WGK: WGK 3
• 闪点(°F): Not applicable
• 闪点(°C): Not applicable