673064

双聚氯化二(2-甲代烯丙基)钯

• 别名: (2-甲基烯丙基)氯化钯二聚体, Dichlorobis(2-methylallyl)dipalladium
• 线性分子式: [CH₂=C(CH₃)CH₂PdCl]₂
• CAS号: 12081-18-4
• 分子量: 393.94
• MDL號碼: MFCD08561141
• 分類程式碼代碼: 12161600
• PubChem物質ID: 24885140
• NACRES: NA.22

属性

• 形狀: solid
• 反應適用性: core: palladium; reaction type: Buchwald-Hartwig Cross Coupling Reaction; reaction type: Cross Couplings; reaction type: Heck Reaction; reaction type: Hiyama Coupling; reaction type: Negishi Coupling; reaction type: Sonogashira Coupling; reaction type: Stille Coupling; reaction type: Suzuki-Miyaura Coupling; reagent type: catalyst
• mp: 168.2-174.0 °C
• 儲存溫度: 2-8°C
• SMILES 字串: Cl[Pd].Cl[Pd].[CH2][C]([CH2])C.[CH2][C]([CH2])C
• InChI: 1S/2C4H7.2ClH.2Pd/c2*1-4(2)3;;;;/h2*1-2H2,3H3;2*1H;;/q;;;;2*+1/p-2
• InChI 密鑰: XVIHZVZZPKOMRE-UHFFFAOYSA-L

说明

應用

Catalyst for:

• Asymmetric allylic alkylation reactions
• Suzuki-Miyaura reactions
• Reductive cleavage reactions
• Reaction of alkenyloxiranes with carbon monoxide

分析報告

用于有机硅醇交叉偶联反应中钯(I) 催化剂的前体。

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves