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品質等級
化驗
≥94% (GC)
折射率
n20/D 1.414 (lit.)
bp
157-162 °C (lit.)
密度
0.823 g/mL at 25 °C (lit.)
SMILES 字串
CCC(C)CC(=O)CC
InChI
1S/C8H16O/c1-4-7(3)6-8(9)5-2/h7H,4-6H2,1-3H3
InChI 密鑰
PSBKJPTZCVYXSD-UHFFFAOYSA-N
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應用
- 5-Methyl-3-heptanone can be converted into the corresponding gem-dihydroperoxide using aqueous hydrogen peroxide and chlorosulfonic acid as a catalyst at room temperature.
- It can be reduced to its corresponding alcohol using sodium borohydride in urea/choline chloride eutectic salt.
- It can undergo condensation with tert-butyl-sulfinamide to form the corresponding chiral tert-butyl-sulfinyl-ketimine, which can further react with ylides derived from trimethylsulfonium iodide and S-allyl tetrahydrothiophenium bromide to form highly substituted chiral aziridines.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Flam. Liq. 3 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
3 - Flammable liquids
水污染物質分類（WGK）
WGK 1
閃點（°F）
111.2 °F - closed cup
閃點（°C）
44 °C - closed cup
個人防護裝備
Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter
Natural deep eutectic salt promoted regioselective reduction of epoxides and carbonyl compounds.
Azizi N, et al.
Royal Society of Chemistry Advances, 2(6), 2289-2293 (2012)
An efficient synthesis of gem-dihydroperoxides and 1, 2, 4, 5-tetraoxanes catalyzed bychlorosulfonic acid as a new catalyst.?
Khosravi K and Asgari A
JOURNAL OF ADVANCES IN CHEMISTRY, 11(3), 3381-3390 (2015)
Direct synthesis of chiral aziridines from N-tert-butyl-sulfinylketimines.
Morton D, et al.
Chemical Communications (Cambridge, England), (17), 1833-1835 (2006)
Denis Schenkel et al.
Frontiers in microbiology, 9, 1847-1847 (2018-08-29)
The plant-growth modulating effect of microbial volatile organic compounds (VOCs) has been demonstrated repeatedly. This has most often been performed by exposing plants to VOC released by microbes grown on nutrient rich media. Here, we used soil instead to grow
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