578932

N-烯丙基-N,N-双(三甲基甲硅烷基)胺

97%

• 别名: (Prop-2-en-1-yl)bis(trimethylsilyl)amine, 1,1,1-Trimethyl-N-2-propen-1-yl-N-(trimethylsilyl)silanamine, 3-Bis(trimethylsilyl)amino-1-propene, Bis(trimethylsilyl)allylamine, N,N-Bis(trimethylsilyl)-2-propen-1-amine, N,N-Bis(trimethylsilyl)allylamine, N-Allyl-1,1,1-trimethyl-N-(trimethylsilyl)silanamine
• 线性分子式: CH₂=CHCH₂NH[Si(CH₃)₃]₂
• CAS号: 7688-51-9
• 分子量: 201.46
• EC號碼: 231-699-2
• MDL號碼: MFCD00545193
• 分類程式碼代碼: 12352103
• PubChem物質ID: 24880960
• NACRES: NA.22

属性

• 化驗: 97%
• 形狀: liquid
• 折射率: n20/D 1.440 (lit.)
• bp: 72 °C/15 mmHg (lit.)
• 密度: 0.816 g/mL at 25 °C (lit.)
• 官能基: amine
• SMILES 字串: C[Si](C)(C)N(CC=C)[Si](C)(C)C
• InChI: 1S/C9H23NSi2/c1-8-9-10(11(2,3)4)12(5,6)7/h8H,1,9H2,2-7H3
• InChI 密鑰: CVNCFZIIZGNVFD-UHFFFAOYSA-N

说明

應用

N-Allyl-N,N-bis(trimethylsilyl)amine or N,N-bis(trimethylsilyl)prop-2-en-1-amine (AHMDS) can be used as a nucleophilic reagent to prepare:

• Complex bicyclic scaffolds by reacting with aryl aldehydes via imine formation followed by efficient multicomponent reactions.
• Dithiasuccinoyl (Dts) heterocycle by reacting with bisthiocarbamoyl chloride.
• Allyl selenide by reacting with aryl selenium salt in the presence of a ruthenium catalyst; Allyl selenide is utilized as a key intermediate in organic synthesis.

AHMDS can also be used as a reagent in hydrosilylation and hydroboration reaction. It may be also used as an electrolyte additive.

安全信息

• 象形圖: GHS02,GHS07
• 訊號詞: Warning
• 危險聲明: H226,H315,H319,H335
• 防範說明: P210 - P233 - P240 - P241 - P303 + P361 + P353 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 3 - Flammable liquids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: 109.0 °F - closed cup
• 閃點（°C）: 42.78 °C - closed cup
• 個人防護裝備: Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter