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Merck
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文件

538647

Sigma-Aldrich

1-氟十二烷

98%

别名:

正十二烷基氟化物

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About This Item

线性分子式:
F(CH2)11CH3
CAS号:
334-68-9
分子量:
188.33
EC號碼:
206-381-1
MDL號碼:
MFCD00013580
分類程式碼代碼:
12352100
PubChem物質ID:
24878349
NACRES:
NA.22

化驗

98%

折射率

n20/D 1.42 (lit.)

密度

0.807 g/mL at 25 °C (lit.)

SMILES 字串

CCCCCCCCCCCCF

InChI

1S/C12H25F/c1-2-3-4-5-6-7-8-9-10-11-12-13/h2-12H2,1H3

InChI 密鑰

YHYBNVZCQIDLSQ-UHFFFAOYSA-N

相关类别

一般說明

1-Fluorododecane is a long chain 1-fluoroalkane. It can be synthesized from the reaction between 1-dodecanol, N,N-diethyl-α,α-difluoro-[3,5-bis(1H,1H,2H,2H-perfluorodecyl)benzyl]amine and heptane. 1-Fluorododecane undergoes reaction with dibromomethane and titanocene dichloride in the presence of triethyl aluminium (Et3Al) to afford a mixture of 1-chlorododecane and 1-bromododecane. 1-Fluorododecane can also be prepared from 1-hydroxydodecane.

象形圖

Skull and crossbones
GHS06

訊號詞

Danger

危險聲明

H300,H413

危險分類

Acute Tox. 2 Oral - Aquatic Chronic 4

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類（WGK）

WGK 3

閃點（°F）

223.0 °F - closed cup

閃點（°C）

106.1 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter

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Fluorination of alcohols and diols with a novel fluorous deoxy-fluorination reagent.
Furuya T, et al.
Journal of Fluorine Chemistry, 130(2), 348-353 (2009)
Regioselective Hydroxylation of C12?C15 Fatty Acids with Fluorinated Substituents by Cytochrome P450 BM3.
Chiang, Chih-Hsiang, et al.
Chemistry?A European Journal , 19(41), 13680-13691 (2013)
Halogen Exchange Reaction of Aliphatic Fluorine Compounds with Organic Halides as Halogen Source.
Mizukami Y, et al.
Organic Letters, 17(24), 5942-5945 (2015)
Vapor Pressures and Boiling Points of the 1-Fluoroalkanes, 1-Chloroalkanes, 1-Bromoalkanes, and 1-Iodoalkanes, C1to C20.
Li JCM and Rossini RD.
Journal of Chemical and Engineering Data, 6(2), 268-270 (1961)

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