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Merck

461075

Sigma-Aldrich

1-三甲基硅基吡咯酮

96%

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About This Item

经验公式(希尔记法):
C7H15NOSi
CAS号:
分子量:
157.29
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

96%

折射率

n20/D 1.46 (lit.)

bp

90 °C/20 mmHg (lit.)

密度

0.983 g/mL at 25 °C (lit.)

SMILES 字串

C[Si](C)(C)N1CCCC1=O

InChI

1S/C7H15NOSi/c1-10(2,3)8-6-4-5-7(8)9/h4-6H2,1-3H3

InChI 密鑰

LUBVCBITQHEVCJ-UHFFFAOYSA-N

一般說明

1-(Trimethylsilyl)-2-pyrrolidinone has been prepared by refluxing a mixture of 2-pyrrolidinone, triethylamine and trimethylchlorosilane in benzene. It undergoes sulfenylation with phenyl disulfide to form the corresponding bissulfide as the major product.

應用

1-(Trimethylsilyl)-2-pyrrolidinone may be used for the preparation of 1-(diphenylphosphonio)pyrrolidin-2-one and 1-(1-adamantylcarbonyl)-2-pyrrolidinone.

象形圖

FlameExclamation mark

訊號詞

Warning

危險分類

Eye Irrit. 2 - Flam. Liq. 3 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

127.4 °F - closed cup

閃點(°C)

53 °C - closed cup

個人防護裝備

Eyeshields, Faceshields, Gloves, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Synthesis, conformational characteristics and anti-influenza virus A activity of some 2-adamantylsubstituted azacycles.
Setaki D, et al.
Bioorganic Chemistry, 34(5), 248-273 (2006)
Sulfenylation and sulfinylation of lactams and imino ethers.
Zoretic PA, et al.
The Journal of Organic Chemistry, 43(7), 1379-1382 (1978)
Efficient method for the preparation of carboxylic acid alkyl esters or alkyl phenyl ethers by a new-type of oxidation-reduction condensation using 2, 6-dimethyl-1, 4-benzoquinone and alkoxydiphenylphosphines.
Shintou T, et al.
Bulletin of the Chemical Society of Japan, 76(8), 1645-1667 (2003)
Synthesis and antiviral activity evaluation of some new aminoadamantane derivatives. 2.
Kolocouris N, et al.
Journal of Medicinal Chemistry, 39(17), 3307-3318 (1996)

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