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Merck

431338

Sigma-Aldrich

硝酸铈(IV)铵

99.99%

别名:

硝酸铈铵

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About This Item

线性分子式:
Ce(NH4)2(NO3)6
CAS号:
分子量:
548.22
EC號碼:
MDL號碼:
分類程式碼代碼:
12352302
PubChem物質ID:

化驗

99.99%

反應適用性

reagent type: oxidant

雜質

≤0.05% insol. dil. H2SO4
<100 ppm total metallic impurities

負離子痕跡

chloride (Cl-): ≤0.01%
phosphate (PO43-): ≤0.02%

正離子痕跡

Fe: ≤0.005%

SMILES 字串

N.N.[Ce+4].O[N+]([O-])=O.O[N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/Ce.2HNO3.4NO3.2H3N/c;6*2-1(3)4;;/h;2*(H,2,3,4);;;;;2*1H3/q+4;;;4*-1;;

InChI 密鑰

WIBGOERAEYJBOT-UHFFFAOYSA-N

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應用

提供通过温和条件下氧化丙二酸盐得到丙醇二酸衍生物的一种新途径。

特點和優勢

符合 ACS 试剂规范。

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产品编号
说明
价格

訊號詞

Danger

危險分類

Acute Tox. 4 Oral - Aquatic Acute 1 - Aquatic Chronic 1 - Eye Dam. 1 - Met. Corr. 1 - Ox. Sol. 2 - Skin Corr. 1B - Skin Sens. 1A

儲存類別代碼

5.1B - Oxidizing hazardous materials

水污染物質分類(WGK)

WGK 3

個人防護裝備

Eyeshields, Gloves, type P3 (EN 143) respirator cartridges


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分析证书(COA)

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Nair, V. et al.
Tetrahedron Letters, 39, 2801-2801 (1998)
David A Evans et al.
Organic letters, 8(24), 5669-5671 (2006-11-17)
The ceric ammonium nitrate promoted oxidations of 4,5-diphenyloxazoles and oxazoles with various substitution patterns have been investigated. This transformation results in the formation of the corresponding imide in good yield and tolerates a wide variety of functional groups and substituents
Douglas B Grotjahn et al.
Journal of the American Chemical Society, 133(47), 19024-19027 (2011-11-09)
Organometallic iridium complexes have been reported as water oxidation catalysts (WOCs) in the presence of ceric ammonium nitrate (CAN). One challenge for all WOCs regardless of the metal used is stability. Here we provide evidence for extensive modification of many
David Kesselring et al.
Journal of the American Chemical Society, 130(34), 11290-11291 (2008-08-06)
Conditions for a site-selective ceric ammonium nitrate oxidation have been developed. The reactions proceed nicely on both 1K- and 12K-microelectrode arrays. The procedure for developing the reactions was very simple and demonstrated that the same reagents used for a solution-phase
Yue Qi Ye et al.
Bioscience, biotechnology, and biochemistry, 74(11), 2342-2344 (2010-11-13)
The structure of a long-known natural pigment, atromentin, was established by a total synthesis based on double Suzuki-Miyaura coupling and by a single-crystal X-ray analysis of the synthetic sample thereby obtained. A similar strategy including ceric ammonium nitrate (CAN) oxidation

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