419230

(苄氧羰基甲基)三苯基溴化膦

97%

• 线性分子式: C₆H₅CH₂O₂CCH₂P(C₆H₅)₃Br
• CAS号: 78385-36-1
• 分子量: 493.37
• MDL號碼: MFCD00191780
• 分類程式碼代碼: 12352108
• PubChem物質ID: 24866100
• NACRES: NA.22

属性

• 化驗: 97%
• 反應適用性: reaction type: C-C Bond Formation
• mp: 124 °C (dec.) (lit.)
• SMILES 字串: [Br-].O=C(C[P+](c1ccccc1)(c2ccccc2)c3ccccc3)OCc4ccccc4
• InChI: 1S/C27H24O2P.BrH/c28-27(29-21-23-13-5-1-6-14-23)22-30(24-15-7-2-8-16-24,25-17-9-3-10-18-25)26-19-11-4-12-20-26;/h1-20H,21-22H2;1H/q+1;/p-1
• InChI 密鑰: AVQABZVTPWROCF-UHFFFAOYSA-M

说明

應用

Reactant for:

• Atypical aza-Morita-Baylis-Hillman mechanism
• Thermal decomposition
• Double aza-Michael reaction
• Cyclodextrin derivatives
• Stereoselective preparation of α,β-unsaturated carbonyl compounds via stereoselective Wittig olefination with aldehydes under solventless conditions or ultrasonication
• Synthesis of [difluoro(alkenylphenyl)methyl]phosphonic acids on non-crosslinked polystyrene as inhibitors of PTP-1B via Wittig reaction

安全信息

• 象形圖: GHS07
• 訊號詞: Warning
• 危險聲明: H315,H319,H335
• 防範說明: P261 - P264 - P271 - P280 - P302 + P352 - P305 + P351 + P338
• 危險分類: Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
• 標靶器官: Respiratory system
• 儲存類別代碼: 11 - Combustible Solids
• 水污染物質分類（WGK）: WGK 3
• 閃點（°F）: Not applicable
• 閃點（°C）: Not applicable
• 個人防護裝備: dust mask type N95 (US), Eyeshields, Gloves