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About This Item
线性分子式:
FC6H4B(OH)2
CAS号:
分子量:
139.92
Beilstein:
2829653
MDL號碼:
分類程式碼代碼:
12352103
PubChem物質ID:
NACRES:
NA.22
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化驗
≥95%
形狀
powder
mp
262-265 °C (lit.)
SMILES 字串
OB(O)c1ccc(F)cc1
InChI
1S/C6H6BFO2/c8-6-3-1-5(2-4-6)7(9)10/h1-4,9-10H
InChI 密鑰
LBUNNMJLXWQQBY-UHFFFAOYSA-N
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應用
4-氟基苯硼酸可用作反应物，参与四氟硼酸芳香重氮盐、 碘鎓盐和碘烷的偶联反应。它还被用于生产具有生物活性的新型三联苯。
它也可作为反应物参与：
它也可作为反应物参与：
- 使用微波和triton B催化剂的Suzuki偶联。
- Pd催化的吡唑与苯硼酸的直接芳基化反应。
- 钯纳米粒子催化的 Mizoroki-Heck 和 Suzuki-Miyaura 偶联反应。
- Cu催化的Petasis反应。
- 串联型Pd(II)催化的氧化Heck反应和分子内C-H酰胺化序列。
- 钌催化的直接芳基化。
- Rh催化的不对称耦合物加合。
- 无配体铜催化的硝基芳烃与芳基硼酸的偶联。
- 通过Suzuki-Miyaura和Sonogashira交叉偶联反应进行区域选择性芳基化和炔基化。
- 四溴噻吩的Suzuki交叉偶联。
- 腈的钯催化加成。
其他說明
含不定量的酸酐
訊號詞
Warning
危險分類
Acute Tox. 4 Oral - Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 3
閃點（°F）
Not applicable
閃點（°C）
Not applicable
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
其他客户在看
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The Journal of organic chemistry, 61(14), 4720-4724 (1996-07-12)
The palladium-catalyzed cross-coupling reaction of iodinanes (iodonium salts and iodanes) with organoboron compounds to form carbon-carbon bonds was achieved at ambient temperature under aqueous conditions in the absence of base. Coupling of phenylboronic acid with diphenyliodonium tetrafluoroborate in the presence
J J Li et al.
Journal of medicinal chemistry, 39(9), 1846-1856 (1996-04-26)
A novel series of terphenyl methyl sulfones and sulfonamides have been shown to be highly potent and selective cyclooxygenase-2 (COX-2) inhibitors. The sulfonamide analogs 17 and 21 were found to be much more potent COX-2 inhibitors and orally active anti-inflammatory
Robin Frauenlob et al.
The Journal of organic chemistry, 77(9), 4445-4449 (2012-04-13)
We have developed a copper-catalyzed process for the coupling of aldehydes, amines, and boronic acids. This allows greater reactivity with simple aryl boronic acids and allows coupling reactions to proceed that previously failed. Initial mechanistic studies support a process involving
Microwave-enhanced triton B catalyzed Suzuki coupling reaction
Meshram, H. M.; et al.
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