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化驗
95%
形狀
liquid
折射率
n20/D 1.415 (lit.)
bp
91-93 °C/11 mmHg (lit.)
密度
0.954 g/mL at 25 °C (lit.)
官能基
ether
nitrile
SMILES 字串
CCOC(CC#N)OCC
InChI
1S/C7H13NO2/c1-3-9-7(5-6-8)10-4-2/h7H,3-5H2,1-2H3
InChI 密鑰
WBOXEOCWOCJQNK-UHFFFAOYSA-N
一般說明
3,3-Diethoxypropionitrile is a cyanide derivative. It undergoes reaction with urea in refluxing butanolic sodium butoxide to afford 4-amino-2(1H)-pyrimidinone and cytosine. Its physical properties (density, refractive index, boiling point and melting point) have been reported.
應用
3,3-Diethoxypropionitrile may be used in the synthesis of 2-(2,2-diethoxy-ethyl)-pyridine, via [2+2+2]-cycloaddition reaction. It may be used in the synthesis of cyanomalondialdehyde.
訊號詞
Warning
危險聲明
危險分類
Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3
標靶器官
Respiratory system
儲存類別代碼
10 - Combustible liquids
水污染物質分類(WGK)
WGK 2
閃點(°F)
183.2 °F - closed cup
閃點(°C)
84 °C - closed cup
個人防護裝備
Eyeshields, Gloves, type ABEK (EN14387) respirator filter
Preparation, Structure, and Reactions of Halomalondialehdes.
Angewandte Chemie (International Edition in English), 14(2), 86-94 (1975)
The Chemistry of Heterocyclic Compounds, 216-216 (2009)
Synthesis of isoxazole.
Chemical Reagents, 1, 027-027 (2010)
The Yaws Handbook of Physical Properties for Hydrocarbons and Chemicals, 164-164 (2015)
The Journal of organic chemistry, 67(13), 4414-4422 (2002-06-22)
The photocatalyzed [2 + 2 + 2]-cycloaddition of nitriles with 2 equiv of acetylene to 2-pyridines can be carried out under mild conditions and represents a valuable extension to common synthetical methods. For the ideal wavelength range (350-500 nm), lamps
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