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Merck

345458

Sigma-Aldrich

三氯化硼 溶液

1.0 M in p-xylene

别名:

Boron chloride, Trichloroborane

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About This Item

经验公式(希尔记法):
BCl3
CAS号:
分子量:
117.17
MDL號碼:
分類程式碼代碼:
12352106
PubChem物質ID:
NACRES:
NA.22

蒸汽密度

4.03 (vs air)

蒸汽壓力

1 mmHg ( 12.7 °C)

形狀

liquid

反應適用性

core: boron
reagent type: Lewis acid
reagent type: catalyst

濃度

1.0 M in p-xylene

密度

0.901 g/mL at 25 °C

SMILES 字串

ClB(Cl)Cl

InChI

1S/BCl3/c2-1(3)4

InChI 密鑰

FAQYAMRNWDIXMY-UHFFFAOYSA-N

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相关类别

應用

用于制备脂肪酸甲酯以及用于三酸甘油酯的酯交换反应。

訊號詞

Danger

危險分類

Acute Tox. 2 Oral - Acute Tox. 3 Inhalation - Acute Tox. 4 Dermal - Aquatic Chronic 3 - Asp. Tox. 1 - Eye Dam. 1 - Flam. Liq. 3 - Repr. 1B - Skin Corr. 1B - STOT SE 3

標靶器官

Respiratory system

安全危害

儲存類別代碼

3 - Flammable liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

84.2 °F - closed cup

閃點(°C)

29 °C - closed cup

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


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Warwick J Belcher et al.
Dalton transactions (Cambridge, England : 2003), (12)(12), 1602-1614 (2008-03-13)
The reactions of boron halides with free base porphyrins under conditions where partial hydrolysis of the boron halides can occur give diboron porphyrin complexes containing BOB moieties in which each boron is bonded to two porphyrin nitrogen atoms. BF(3).OEt(2) with
Dean Marković et al.
Chemistry (Weinheim an der Bergstrasse, Germany), 16(20), 5969-5975 (2010-04-17)
The first ene reactions of SO(2) and unfunctionalized alkenes are reported. Calculations suggest that the endergonic ene reactions of SO(2) with alkenes can be used to generate beta,gamma-unsaturated sulfinyl and sulfonyl compounds. Indeed, in the presence of one equivalent of
C Matthäus et al.
Spectrochimica acta. Part A, Molecular and biomolecular spectroscopy, 57(3), 521-534 (2001-04-13)
A method for expressing quantitatively the vibrational normal modes of a molecule in a basis set consisting of the normal vibrations (plus translations and rotations) of its constituent fragments is presented. The method is illustrated by describing the vibrational modes
Guillaume Reinisch et al.
The journal of physical chemistry. A, 115(18), 4786-4797 (2011-04-16)
We report on a theoretical study of the gas-phase decomposition of boron trichloride in the presence of hydrogen radicals using ab initio energetic calculations coupled to TST, RRKM, and VTST-VRC kinetic calculations. In particular, we present an addition-elimination mechanism (BCl(3)
Robert Winker et al.
International archives of occupational and environmental health, 81(4), 423-428 (2007-07-27)
To examine whether semiconductor workers exposed to complex mixtures of chemical waste show an increase in genotoxic effects, and, if so, whether occupational safety measures protect these workers. To assess chemical exposure in the workplace, air monitoring of boron trifluoride

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