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Merck

330205

Sigma-Aldrich

5-氯-1-甲基咪唑

98%

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About This Item

经验公式(希尔记法):
C4H5ClN2
CAS号:
分子量:
116.55
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22

化驗

98%

形狀

liquid

折射率

n20/D 1.511 (lit.)

bp

82-85 °C/11 mmHg (lit.)

密度

1.25 g/mL at 25 °C (lit.)

SMILES 字串

Cn1cncc1Cl

InChI

1S/C4H5ClN2/c1-7-3-6-2-4(7)5/h2-3H,1H3

InChI 密鑰

NYDGOZPYEABERA-UHFFFAOYSA-N

一般說明

5-Chloro-1-methylimidazole is a 5-halo-1-methylimidazole. It participates in electron-rich iron(III) porphyrin complex catalyzed epoxidation of olefins.

應用

5-Chloro-1-methylimidazole was used in synthesis of C-5 functionalized N-methylated imidazoles.

象形圖

Exclamation mark

訊號詞

Warning

危險聲明

危險分類

Eye Irrit. 2 - Skin Irrit. 2 - STOT SE 3

標靶器官

Respiratory system

儲存類別代碼

10 - Combustible liquids

水污染物質分類(WGK)

WGK 3

閃點(°F)

204.8 °F - closed cup

閃點(°C)

96 °C - closed cup

個人防護裝備

Eyeshields, Gloves, type ABEK (EN14387) respirator filter


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An efficient route to 5-iodo-1-methylimidazole: synthesis of xestomanzamine A.
Panosyan FB and Still IWJ.
Canadian Journal of Chemistry, 79(7), 1110-1114 (2001)
W Nam et al.
Journal of inorganic biochemistry, 80(3-4), 219-225 (2000-09-23)
An electron-rich iron(III) porphyrin complex (meso-tetramesitylporphinato)iron(III) chloride [Fe(TMP)Cl], was found to catalyze the epoxidation of olefins by aqueous 30% H2O2 when the reaction was carried out in the presence of 5-chloro-1-methylimidazole (5-Cl-1-Melm) in aprotic solvent. Epoxides were the predominant products

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