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About This Item
线性分子式:
(CH3)2C(OCOCH3)COCl
CAS号:
分子量:
164.59
Beilstein:
507772
EC號碼:
MDL號碼:
分類程式碼代碼:
12352100
PubChem物質ID:
NACRES:
NA.22
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化驗
95%
形狀
liquid
折射率
n20/D 1.428 (lit.)
bp
55-56 °C/6 mmHg (lit.)
密度
1.136 g/mL at 25 °C (lit.)
SMILES 字串
CC(=O)OC(C)(C)C(Cl)=O
InChI
1S/C6H9ClO3/c1-4(8)10-6(2,3)5(7)9/h1-3H3
InChI 密鑰
RBTCRFLJLUNCLL-UHFFFAOYSA-N
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一般說明
Reaction of 1-chlorocarbonyl-1-methylethyl acetate with 1-aryl ethylene glycols to yield trans chlorohydrin acetates was reported.
應用
1-Chlorocarbonyl-1-methylethyl acetate was used in preparation of α,γ-dichloro alditols.
訊號詞
Danger
危險聲明
危險分類
Skin Corr. 1B
安全危害
儲存類別代碼
8A - Combustible corrosive hazardous materials
水污染物質分類（WGK）
WGK 3
閃點（°F）
154.4 °F - closed cup
閃點（°C）
68 °C - closed cup
個人防護裝備
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
Mahesh K Lakshman et al.
Journal of the American Chemical Society, 129(1), 68-76 (2007-01-04)
A diastereoselective synthesis of the nucleoside adducts corresponding to a cis ring-opening of the carcinogen (+/-)-7 beta, 8 alpha-dihydroxy-9 alpha,10 alpha-epoxy-7,8,9,10-tetrahydrobenzo[a]pyrene (BaP DE-2) by 2'-deoxyadenosine and 2'-deoxyguanosine is described. The key intermediate (+/-)-10alpha-amino-7beta,8alpha,9alpha-trihydroxy-7,8,9,10-tetrahydrobenzo[a]pyrene was synthesized by a highly diastereoselective dihydroxylation
Efficient synthesis of some dichloroalditols: direct regioselective chlorination of some unprotected alditols by 1-chlorocarbonyl-1-methylethyl acetate.
Benazza M, et al.
Journal of Carbohydrate Chemistry, 13(7), 967-979 (1994)
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