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Merck

295027

Sigma-Aldrich

三氟化硼

≥99.5%

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About This Item

经验公式(希尔记法):
BF3
CAS号:
分子量:
67.81
EC 号:
MDL编号:
UNSPSC代码:
12352106
PubChem化学物质编号:
NACRES:
NA.22

蒸汽密度

2.38 (21 °C, vs air)

方案

≥99.5%

表单

gas

反应适用性

core: boron
reagent type: Lewis acid
reagent type: catalyst
reaction type: Polymerization Reactions

沸点

−100 °C (lit.)

mp

−127 °C (lit.)

SMILES字符串

FB(F)F

InChI

1S/BF3/c2-1(3)4

InChI key

WTEOIRVLGSZEPR-UHFFFAOYSA-N

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警示用语:

Danger

危险声明

危险分类

Acute Tox. 2 Inhalation - Eye Dam. 1 - Press. Gas Compr. Gas - Skin Corr. 1A

补充剂危害

储存分类代码

2A - Gases

WGK

WGK 1

个人防护装备

Faceshields, Gloves, Goggles, multi-purpose combination respirator cartridge (US)


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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G K Surya Prakash et al.
Organic letters, 13(15), 4128-4131 (2011-07-14)
The one-pot synthesis of 1,1,1-trifluoro- and 1,1-difluoro-2,2-diarylethanes from arenes and fluorinated hemiacetals in the BF(3)-H(2)O system is described. The reaction is simple, clean, and convenient, eliminating the use of organic solvents and other expensive acid systems. BF(3)-H(2)O is economic, is
Brieuc Guillerm et al.
Macromolecular rapid communications, 33(19), 1600-1612 (2012-07-05)
Polyoxazolines (POx) are increasingly being studied as polymeric building blocks due to the possibility of affording tunable properties. Additionally, as the biocompatibility and stealth behavior of POx are similar to that of poly(ethylene glycol) (PEG), it has become challenging to
Ahmad Makahleh et al.
Talanta, 81(1-2), 20-24 (2010-03-02)
A reversed-phase high-performance liquid chromatographic method with capacitively coupled contactless conductivity detector (C(4)D) has been developed for the separation and the simultaneous determination of five underivatized long chain fatty acids (FAs), namely myristic, palmitic, stearic, oleic, and linoleic acids. An
Nolan R Mente et al.
The Journal of organic chemistry, 73(20), 7963-7970 (2008-09-18)
The total synthesis of the natural stilbene (+)-schweinfurthin G (8) has been accomplished through a sequence based on an efficient cationic cascade cyclization. This cascade process is initiated by Lewis acid promoted ring opening of an epoxide and terminated through
G K Surya Prakash et al.
The Journal of organic chemistry, 74(22), 8659-8668 (2009-10-30)
BF(3)-monohydrate is found to be an efficient and strong acid catalyst as well as an effective protosolvating medium suitable for the hydroxyalkylation of arenes with aromatic aldehydes. This reaction has been extended to aromatic dialdehydes, such as terephthalic dicarboxaldehyde and

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