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方案
≥97.0%
折射率
n20/D 1.573 (lit.)
n20/D 1.573
沸点
245 °C (lit.)
50 °C/0.2 mmHg (lit.)
密度
1.225 g/mL at 25 °C (lit.)
官能团
chloro
储存温度
2-8°C
SMILES字符串
Cc1ccc(OC(Cl)=S)cc1
InChI
1S/C8H7ClOS/c1-6-2-4-7(5-3-6)10-8(9)11/h2-5H,1H3
InChI key
UNCAXIZUVRKBMN-UHFFFAOYSA-N
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应用
O-(p-Tolyl) chlorothionoformate has been used in the synthesis of:
- α-L-2′-deoxythreofuranosyl nucleoside analogs
- alkenes from hindered alcohols
其他说明
由位阻醇合成烯烃
警示用语：
Danger
危险声明
危险分类
Acute Tox. 3 Inhalation - Skin Corr. 1B
储存分类代码
6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials
WGK
WGK 3
闪点(°F)
204.8 °F - closed cup
闪点(°C)
96 °C - closed cup
个人防护装备
Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter
历史批次信息供参考:
分析证书(COA)
Lot/Batch Number
A.P. Neary et al.
Journal of the Chemical Society. Chemical Communications, 1090-1090 (1989)
H. Gerlach et al.
Helvetica Chimica Acta, 55, 2277-2277 (1972)
Kiran S Toti et al.
European journal of medicinal chemistry, 46(9), 3704-3713 (2011-06-15)
The synthesis of a series of α-L-2'-deoxythreofuranosyl nucleosides featuring the nucleobases A, T, C and U is described in seven steps from 1,2-O-isopropyledene-α-L-threose, involving a Vorbrüggen coupling and a Barton-McCombie deoxygenation protocol as the key steps. All analogues, including a
H. Gerlach et al.
Journal of the Chemical Society. Chemical Communications, 1215-1215 (1972)
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