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化驗
99%
形狀
liquid
折射率
n20/D 1.534 (lit.)
bp
248 °C (lit.)
密度
1.157 g/mL at 25 °C (lit.)
SMILES 字串
COC(=O)c1ccccc1OC
InChI
1S/C9H10O3/c1-11-8-6-4-3-5-7(8)9(10)12-2/h3-6H,1-2H3
InChI 密鑰
PFYHAAAQPNMZHO-UHFFFAOYSA-N
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一般說明
FeCl2 catalyzed cross-coupling reaction between methyl 2-methoxybenzoate and diphenylmethane under various reaction conditions has been investigated.
應用
Methyl 2-methoxybenzoate has been used in the synthesis of (+/−)-vibralactone.
儲存類別代碼
11 - Combustible Solids
水污染物質分類（WGK）
WGK 2
閃點（°F）
235.4 °F - closed cup
閃點（°C）
113 °C - closed cup
個人防護裝備
dust mask type N95 (US), Eyeshields, Gloves
Yi-Zhou Li et al.
Angewandte Chemie (International ed. in English), 48(21), 3817-3820 (2009-04-18)
Hooking up: FeCl(2) catalyzes the efficient cross dehydrogenative arylation of substrates having benzylic C-H bonds (see scheme). High regioselectivity was observed during the cross-coupling between compounds containing aromatic C(sp(2))-H bonds and benzylic C(sp(3))-H bonds. This process is proposed to proceed
Quan Zhou et al.
Organic letters, 10(7), 1401-1404 (2008-03-04)
Reductive alkylation of methyl 2-methoxybenzoate with prenyl bromide and hydrolysis afforded methyl 6-oxo-1-prenyl-2-cyclohexenecarboxylate. Reduction of the ketone, hydrolysis, iodolactonization, ozonolysis, and intramolecular aldol reaction provided a spiro lactone cyclopentenal. Retro-iodolactonization with activated Zn, formation of the beta-lactone, and reduction of
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