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Merck

249955

Sigma-Aldrich

氯化锡(IV) 溶液

1.0 M in methylene chloride

别名:

四氯化锡, 氯化高锡

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About This Item

线性分子式:
SnCl4
CAS号:
分子量:
260.52
MDL號碼:
分類程式碼代碼:
12352106
PubChem物質ID:
NACRES:
NA.22

形狀

liquid

品質等級

反應適用性

core: tin
reagent type: catalyst

濃度

1.0 M in methylene chloride

密度

1.419 g/mL at 25 °C

SMILES 字串

Cl[Sn](Cl)(Cl)Cl

InChI

1S/4ClH.Sn/h4*1H;/q;;;;+4/p-4

InChI 密鑰

HPGGPRDJHPYFRM-UHFFFAOYSA-J

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相关类别

一般說明

氯化锡(IV)具有路易斯酸的特征,并通常通过溶胶-凝胶法用于合成SnO2纳米颗粒。

應用

氯化锡(IV)溶液可用于聚砜的氯甲基化反应,以开发聚合物电解质膜。

包裝

推荐将25毫升安全/密封瓶作为一次性使用的瓶子。重复穿刺可能会导致产品性能下降。

法律資訊

Sure/Seal is a trademark of Sigma-Aldrich Co. LLC

訊號詞

Danger

危險分類

Aquatic Chronic 3 - Carc. 2 - Eye Dam. 1 - Skin Corr. 1B - STOT SE 3

標靶器官

Central nervous system, Respiratory system

儲存類別代碼

6.1A - Combustible acute toxic Cat. 1 and 2 / very toxic hazardous materials

水污染物質分類(WGK)

WGK 2

閃點(°F)

Not applicable

閃點(°C)

Not applicable

個人防護裝備

Faceshields, Gloves, Goggles, type ABEK (EN14387) respirator filter


历史批次信息供参考:

分析证书(COA)

Lot/Batch Number

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Solid-State and Solution Structural Study of Acetylacetone-Modified Tin (IV) Chloride Used as a Precursor of SnO2 Nanoparticles Prepared by a Sol- Gel Route.
Briois V, et al.
Chemistry of Materials, 16(20), 3885-3894 (2004)
Phosphoric acid doped polysulfone membranes with aminopyridine pendant groups and imidazole cross-links.
Hink S, et al.
European Polymer Journal, 72(20), 102-113 (2015)
Molecular addition compounds of tin (IV) chloride. I. Interaction with benzonitriles in benzene solution.
Brown TL and Kubota M
Journal of the American Chemical Society, 83(2), 331-334 (1961)
Gerry A Griffith et al.
Journal of the American Chemical Society, 128(40), 13130-13141 (2006-10-05)
Difluorinated alkenoate ethyl 3,3-difluoro-2-(N,N-diethylcarbamoyloxy)-2-propenoate reacts rapidly and in high yield with furan and a range of substituted furans in the presence of a tin(IV) catalyst. Non-fluorinated congener 2-(N,N-diethylcarbamoyloxy)-2-propenoate fails to react at all under the same conditions. These reactions have
Yasuyuki Kita et al.
The Journal of organic chemistry, 71(14), 5191-5197 (2006-07-01)
The Lewis acid-promoted rearrangement of 2,2,3,3-tetrasubstituted 2,3-epoxy alcohols with several kinds of protecting groups was investigated. When SnCl4 is used as a Lewis acid, the reaction proceeds in a regio- and stereo-controlled manner to afford two types of carbonyl compounds

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