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化驗
97%
形狀
liquid
折射率
n20/D 1.401 (lit.)
bp
44-45.5 °C/9 mmHg (lit.)
密度
1.007 g/mL at 25 °C (lit.)
SMILES 字串
CCOC(=O)COC
InChI
1S/C5H10O3/c1-3-8-5(6)4-7-2/h3-4H2,1-2H3
InChI 密鑰
JLEKJZUYWFJPMB-UHFFFAOYSA-N
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應用
Ethyl methoxyacetate was used:
- as acyl donor during the preparation of enantiomers of several phenylethylamines
- as acylation reagent for the aminolysis of 1-phenylethanamine
- in an industrial, lipase-catalysed kinetic resolution of primary amine
Organic & biomolecular chemistry, 9(23), 8171-8177 (2011-10-06)
Both enantiomers of several phenylethylamines, structurally related to amphetamine, have been prepared in good yields and excellent enantiomeric purity by enzymatic kinetic resolution using CAL-B and ethyl methoxyacetate as the acyl donor. In the case of the 4-hydroxyderivative of amphetamine
Organic & biomolecular chemistry, 1(14), 2405-2415 (2003-09-06)
Commonly, hydrolase-catalysed reactions are used for kinetic resolutions of alcohols, amines and acids. Only a few applications in total syntheses have been described. Most of these examples are for the synthesis of amides and peptides. Here, the synthesis of all
Molecules (Basel, Switzerland), 25(4) (2020-02-23)
The enantiomers of aromatic 4-dibenzocyclooctynol (DIBO), used for radiolabeling and subsequent conjugation of biomolecules to form radioligands for positron emission tomography (PET), were separated by kinetic resolution using lipase A from Candida antarctica (CAL-A). In optimized conditions, (R)-DIBO [(R)-1, ee
Biotechnic & histochemistry : official publication of the Biological Stain Commission, 74(1), 40-48 (1999-04-06)
An in situ hybridization procedure resulting in both high resolution and sensitivity was established by using the removable methyl methacrylate resin, Technovit 9100. Young bicellular pollen of tobacco (Nicotiana tabacum L. SR-1) was embedded in Technovit 9100 resin and sectioned.
Journal of biomaterials science. Polymer edition, 21(14), 1925-1935 (2010-06-23)
We have previously reported the hydration structure of a poly(2-methoxyethyl acrylate) (PMEA) antithrombogenic material. In the present study, the hydration structure of a 2-methoxyethyl acetate (MEAc) model monomer for PMEA was explored by means of attenuated total reflection infrared (ATR-IR)
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