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Merck
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文件

219533

Sigma-Aldrich

1-硝基-1-环己烯

99%

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About This Item

经验公式（希尔记法）:
C6H9NO2
CAS号:
2562-37-0
分子量:
127.14
EC號碼:
219-883-0
MDL號碼:
MFCD00001540
分類程式碼代碼:
12352100
PubChem物質ID:
24853132
NACRES:
NA.22

化驗

99%

形狀

liquid

折射率

n20/D 1.505 (lit.)

bp

66-68 °C/1.5 mmHg (lit.)

密度

1.127 g/mL at 25 °C (lit.)

儲存溫度

2-8°C

SMILES 字串

[O-][N+](=O)C1=CCCCC1

InChI

1S/C6H9NO2/c8-7(9)6-4-2-1-3-5-6/h4H,1-3,5H2

InChI 密鑰

DJBRXNRKYAWTBL-UHFFFAOYSA-N

相关类别

一般說明

1-硝基-1-环己烯的化学选择性氢化是由负载在TiO2或Fe2O3上的金纳米粒子所催化的。

應用

1-硝基-1-环己烯可通过负载的金纳米粒子（Au/TiO2及Au/Fe2O3）所催化的化学选择性加氢用于制备取代苯胺。

象形圖

Exclamation mark
GHS07

訊號詞

Warning

危險聲明

H319

危險分類

Eye Irrit. 2

儲存類別代碼

10 - Combustible liquids

水污染物質分類（WGK）

WGK 3

閃點（°F）

174.2 °F - closed cup

閃點（°C）

79 °C - closed cup

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环己烯 contains 100 ppm BHT as inhibitor, ≥99.0%

Sigma-Aldrich

29240

环己烯

Avelino Corma et al.
Nature protocols, 1(6), 2590-2595 (2007-04-05)
A protocol for the chemoselective hydrogenation of nitro compounds to the corresponding anilines by means of supported gold catalysts is described. Nitro groups on different compounds--containing double bonds, carbonyl, nitrile or amide groups--have been successfully hydrogenated on supported gold nanoparticles
Avelino Corma et al.
Science (New York, N.Y.), 313(5785), 332-334 (2006-07-22)
The selective reduction of a nitro group when other reducible functions are present is a difficult process that often requires stoichiometric amounts of reducing agents or, if H2 is used, the addition of soluble metals. Gold nanoparticles supported on TiO2
Fabian Niedermair et al.
Inorganic chemistry, 49(20), 9333-9342 (2010-09-16)
A series of π-extended phosphorescent palladium(II) and platinum(II) porphyrin complexes were synthesized, in which additional benzene rings are fused radially onto at least one of the four peripheral benzo groups. The photophysical properties of the metalloporphyrins palladium(II)-meso-tetra-(4-fluorophenyl)mononaphthotribenzoporphyrin (Pd1NF), cis-palladium(II)-meso-tetra-(4-fluorophenyl)dibenzodinaphthoporphyrin (Pd2NF)

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