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应用
用于 α,ß-不饱和酮的铑催化 α-三氟甲基化反应的试剂。
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法律信息
Aldrich is a registered trademark of Sigma-Aldrich Co. LLC
Sure/Pac is a trademark of Sigma-Aldrich Co. LLC
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价格
通常也和此产品一起购买
警示用语：
Warning
危险声明
危险分类
Muta. 2 - Ozone 1 - Press. Gas Compr. Gas
储存分类代码
2A - Gases
WGK
WGK 1
闪点(°F)
Not applicable
闪点(°C)
Not applicable
个人防护装备
Eyeshields, Gloves
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D E Dodd et al.
Fundamental and applied toxicology : official journal of the Society of Toxicology, 35(1), 64-77 (1997-01-01)
Trifluoroiodomethane (CF3I) is being considered as a replacement compound for halon fire suppressants. Its structure is similar to that of Halon 1301 (CF3Br), but it has very low ozone depletion potential compared to CF3Br. As part of the process of
Discovering and verifying elusive fullerene cage isomers: structures of C2-p11-(C74-D3h)(CF3)12 and C2-p11-(C(78)-D3h5)(CF3)12.
Natalia B Shustova et al.
Angewandte Chemie (International ed. in English), 46(22), 4111-4114 (2007-04-25)
Kelvin Anggara et al.
Science advances, 4(10), eaau2821-eaau2821 (2018-10-13)
Collision geometry is central to reaction dynamics. An important variable in collision geometry is the miss-distance between molecules, known as the "impact parameter." This is averaged in gas-phase molecular beam studies. By aligning molecules on a surface prior to electron-induced
A Vinegar et al.
American Industrial Hygiene Association journal, 60(3), 403-408 (1999-07-01)
Of the agents under consideration for protecting unoccupied areas from fire, CF3I (trifluoroiodomethane) has physicochemical properties that give it potential as a "drop-in" replacement for halon 1301. One of the issues concerning the use of CF3I is the potential hazard
Yingda Ye et al.
Journal of the American Chemical Society, 134(22), 9034-9037 (2012-05-26)
This communication describes the development of a mild method for the cross-coupling of arylboronic acids with CF(3)I via the merger of photoredox and Cu catalysis. This method has been applied to the trifluoromethylation of electronically diverse aromatic and heteroaromatic substrates
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In 2001, Professor William Dolbier, Jr., at the University of Florida reported1 an approach to nucleophilic trifluoromethylation based on the generation of a trifluoromethyl anion using CF3I in the presence of a powerful twoelectron reductant, tetrakis(dimethylamino)ethylene (TDAE)
在2001年，佛罗里达大学的William Dolbier，Jr.教授报告了一种亲核三氟甲基化的方法，该方法基于在强力双电子还原剂四（二甲基氨基）乙烯（TDAE）存在下使用CF3I生成三氟甲基阴离子。
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