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163015

Sigma-Aldrich

硝酸铊(III) 三水合物

别名:

TTN, 三硝酸铊

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About This Item

线性分子式:
Tl(NO3)3 · 3H2O
CAS号:
13453-38-8
分子量:
444.44
EC 号:
237-325-4
MDL编号:
MFCD00149874
UNSPSC代码:
12161600
PubChem化学物质编号:
24850018
NACRES:
NA.22

质量水平

100

反应适用性

core: thallium
reagent type: catalyst

mp

102-105 °C (lit.)

SMILES字符串

O.O.O.[Tl+3].[O-][N+]([O-])=O.[O-][N+]([O-])=O.[O-][N+]([O-])=O

InChI

1S/3NO3.3H2O.Tl/c3*2-1(3)4;;;;/h;;;3*1H2;/q3*-1;;;;+3

InChI key

ZCPIKMRXMBJLCP-UHFFFAOYSA-N

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应用

本试剂可用于将苯乙烯衍生物快速氧化成羰基化合物，用于通过氧化重排进行环芳烷基酮的区域选择性扩环反应，用于硫缩醛到羰基化合物的选择性水解以及用于 19-降甾族化合物的一般合成方法。介导环酮的缩环反应，生成一系列反式稠合的 10-甲基-2-萘烷酮。

警示用语：

Danger

危险分类

Acute Tox. 2 Inhalation - Acute Tox. 2 Oral - Aquatic Chronic 2 - STOT RE 2

储存分类代码

5.1B - Oxidizing hazardous materials

WGK

WGK 3

闪点(°F)

Not applicable

闪点(°C)

Not applicable

历史批次信息供参考:

分析证书(COA)

Lot/Batch Number
STBG4277V
STBJ6769
STBG3606V
STBG3605V
STBG3600V

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Kevin Yauy et al.
The Journal of molecular diagnostics : JMD, 20(4), 465-473 (2018-04-25)
Interpretation of next-generation sequencing constitutes the main limitation of molecular diagnostics. In diagnosing myopathies and muscular dystrophies, another issue is efficiency in predicting the pathogenicity of variants identified in large genes, especially TTN; current in silico prediction tools show limitations
Enrico Bugiardini et al.
Frontiers in neurology, 9, 456-456 (2018-07-13)
Objective: Distal myopathies are a diagnostically challenging group of diseases. We wanted to understand the value of MRI in the current clinical setting and explore the potential for optimizing its clinical application. Methods: We retrospectively audited the diagnostic workup in
Synthetic Communications, 9, 301-301 (1979)
Journal of the American Chemical Society, 98, 3037-3037 (1976)
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Experimental physiology, 102(9), 1055-1066 (2017-08-02)
What is the topic of this review? This review focuses on how in vivo and molecular measurements of cardiac passive stiffness can predict exercise tolerance and how exercise training can reduce cardiac passive stiffness. What advances does it highlight? This
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